Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Excess Molar Volumes and Viscosities for Binary Mixtures of Cyclohexanone with Methacrylic Acid, Benzyl Methacrylate, and 2-Hydroxyethyl Methacrylate at (298.15, 308.15, and 318.15) K

Chen, J. -T.[Jui-Tang], Chang, W.-C.[Wong-Chao]
J. Chem. Eng. Data 2006, 51, 1, 88-92
ABSTRACT
Densities and viscosities at (298.15, 308.15, and 318.15) K are presented as a function of mixture composition for the binary mixtures of cyclohexanone with methacrylic acid, benzyl methacrylate, and 2-hydroxyethyl methacrylate. From the experimental data, the excess molar volumes and viscosity deviations have been calculated. These results have been correlated with the Redlich-Kister type polynomial to derive the coefficients and average absolute deviation (AAD). McAllister's three-body and four-body interaction models were also used to correlate the kinematic viscosities.
Compounds
# Formula Name
1 C6H10O cyclohexanone
2 C4H6O2 2-methyl-2-propenoic acid
3 C11H12O2 benzyl methacrylate
4 C6H10O3 2-hydroxyethyl 2-methyl-2-propenoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 3
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 3
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 3
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 3
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 3
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 3
  • POMD
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:8
  • 3
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 3
  • POMD
  • 1
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 33
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 33
  • POMD
  • 1
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:8
  • 33
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 33
  • POMD
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 33
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 33