ABSTRACT

Densities and viscosities of binary mixtures of propylene glycol monomethyl ether acetate with methacrylic acid, benzyl methacrylate, and 2-hydroxyethyl methacrylate were measured at temperatures from 298.15 K to 318.15 K. A pycnometer and a Cannon-Fenske routine viscometer were used to determine density and kinematic viscosity, respectively. The excess molar volumes (VE) and viscosity deviations (ae) were calculated from the experimental data and were correlated by a Redlich-Kister type polynomial. McAllister s three-body and four-body interaction models were also used to correlate the kinematic viscosities.

Compounds

#	Formula	Name
1	C6H12O3	1-methoxy-2-propyl acetate
2	C11H12O2	benzyl methacrylate
3	C6H10O3	2-hydroxyethyl 2-methyl-2-propenoate
4	C4H6O2	2-methyl-2-propenoic acid

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	1 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	1 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33
POMD	1 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	1 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33
POMD	4 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities and Viscosities of Binary Mixtures of Propylene Glycol Monomethyl Ether Acetate with Methacrylic Acid, Benzyl Methacrylate, and 2-Hydroxyethyl Methacrylate between 298.15 K and 318.15 K

Chen, J. -T.[Jui-Tang], Chang, W.-C.[Wong-Chao]

ABSTRACT