ABSTRACT

Densities, viscosities, and ultrasonic velocities of binary mixtures of chloroform with propan-1-ol and butan-1-ol have been measured over the entire range of composition, at (303.15 and 313.15) K and at atmospheric pressure. From the experimental data, excess molar volumes (V E), deviations in viscosity (centse), and excess isentropic compressibility have been calculated. The excess molar volumes and isentropic compressibility for propan- 1-ol and butan-1-ol are positive while deviations in viscosity are negative. The results have been interpreted in terms of intermolecular interactions. These are further fitted to the Redlich-Kister polynomial equation.

Compounds

#	Formula	Name
1	CHCl3	trichloromethane
2	C3H8O	propan-1-ol
3	C4H10O	butan-1-ol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	2
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:4	2
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:2	2
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	2
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT::UFactor:4	2
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:2	2
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	2
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:4	2
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:2	2
POMD	1 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	42
POMD	1 2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:4	42
POMD	1 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:2	42
POMD	1 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	42
POMD	1 3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:4	42
POMD	1 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:2	42

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Propan-1-ol and Butan-1-ol at (303.15 and 313.15) K

Kadam, U. B.[Ujjan B], Hiray, A. P.[Apoorva P.], Sawant, A. B.[Arun B.], Hasan, M.[Mehdi]

ABSTRACT