Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and Modeling of the High-Pressure Phase Behavior of the Binary System Carbon Dioxide + 1,2-Epoxycyclohexane

van Schilt, M. A.[Marcus A.], Wering, R. M.[Rob M.], Kemmere, M.[Maartje], de Loos, T. W.[Theo W.]
J. Chem. Eng. Data 2005, 50, 6, 1879-1882
ABSTRACT
Experimental bubble point isopleths for the binary system carbon dioxide + 1,2-epoxycyclohexane have been determined for mole fractions from (10 to 50) % CO2 and temperatures from (354 to 424) K. Vapor pressures and liquid densities of pure 1,2-epoxycyclohexane have been measured from (361 to 474) K and from (278 to 363) K, respectively. Using the Peng-Robinson equation of state and van der Waals one-fluid mixing rules, a good description of the phase behavior of both the vapor pressure and the bubble point data has been obtained. The binary interaction parameter kij has been found to be temperature-dependent.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 C6H10O 7-oxabicyclo[4.1.0]heptane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 11
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:8
  • 10
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 40