Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility, Density, and Metastable Zone Width of the (1,4-Dioxan-2-one + Ethyl Acetate) System

Kim, S.-I.[Sung-Il], Kim, C.-U.[Chul-Ung], Park, S.-J.[So-Jin]
J. Chem. Eng. Data 2005, 50, 6, 1871-1874
ABSTRACT
The solubility of 1,4-dioxan-2-one (1) in ethyl acetate (2) was measured over the temperature range from 263.55 K to 295.95 K. The results were correlated by an exponential equation. Densities of their binary mixtures have been measured at temperatures from 263.05 K to 298.55 K and at mole fraction x1 of 0.2010 to 0.7099. The metastable zone width was measured for the evaluation of the nucleation rate and nucleation temperature. Results for the density and the metastable zone width were correlated by empirical equations.
Compounds
# Formula Name
1 C4H6O3 1,4-dioxan-2-one
2 C4H8O2 ethyl acetate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DSC
  • 1
  • POMD
  • 1
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 2
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS:UFactor:4
  • 12
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • BUOYAN
  • 27