Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities of 4-Phenyltoluene, Phenylboric Acid, Biphenyl, and Iodobenzene in Carbon Dioxide from Measurements of the Relative Permittivity

Leeke, G. A.[Gary A.], Santos, R.[Regina], Al-Duri, B.[Bushra], Seville, J.[Jonathan], Smith, C.[Catherine], Holmes, A. B.[Andrew B.]

J. Chem. Eng. Data 2005, 50, 4, 1370-1374

ABSTRACT

Solubility data were obtained for the first time for phenylboric acid, iodobenzene, and biphenyl in carbon dioxide at (353 and 383) K and between pressures of (100 to 300) bar. Data were obtained using a method that used the relative permittivity of the binary mixture. The technique was verified by comparison of solubility data for 4-phenyltoluene that had been determined previously by ourselves using a cloud point technique. The relative permittivity for CO2 was also determined at (353 and 383) K between pressures of (100 to 300) bar.

Compounds

#	Formula	Name
1	C13H12	4-methylbiphenyl
2	C6H7BO2	benzeneboronic acid
3	C12H10	biphenyl
4	C6H5I	iodobenzene
5	CO2	carbon dioxide

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	5 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid Gas	calculated from relative permittivity	10
POMD	2 5	Mole fraction - 5 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid Gas	calculated from relative permittivity	10
POMD	5 4	Mole fraction - 5 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid Gas	calculated from relative permittivity	10
POMD	3 5	Mole fraction - 5 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid Gas	calculated from relative permittivity	10