Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Surface tension of decane binary and ternary mixtures with eicosane, docosane and tetracosane

Queimada, A. J.[Antonio J.], Caco, A. I.[Ana I.], Marrucho, I. M.[Isabel M.], Coutinho, J. A. P.[Joao A. P.]
J. Chem. Eng. Data 2005, 50, 3, 1043-1046
ABSTRACT
A tensiometer operating on the Wilhelmy plate method was employed to measure liquid-vapor interfacial tensions of 3 binary and one ternary mixtures of decane with eicosane, docosane and tetracosane. Binary mixtures n-C10H22 + n-C20H42, n-C10H22 + n-C22H46 and n-C10H22 + n-C24H50 and the ternary n-C10H22 + n-C20H42 + n-C24H50 were measured from 293.15 K (or above the solution melting temperature) up to 343.15 K. An average absolute deviation of 1.3 % was obtained against pure component literature data. No mixture information for the reported systems was found in the literature. Results were modeled with a recently proposed corresponding states model. The average absolute deviation was found to be 1.2 %.
Compounds
# Formula Name
1 C22H46 docosane
2 C24H50 tetracosane
3 C10H22 decane
4 C20H42 eicosane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 3
  • POMD
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 2
  • POMD
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 6
  • POMD
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 4
  • POMD
  • 4
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 24
  • POMD
  • 3
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 19
  • POMD
  • 3
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 16
  • POMD
  • 4
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 3
  • POMD
  • 4
  • 3
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 3; Liquid
  • Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Wilhelmy plate method
  • 22