Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

High-Pressure Vapor-Liquid Equilibria in the System Carbon Dioxide + 1-Butanol at Temperatures from (293.15 to 324.15) K

Secuianu, C.[Catinca], Feroiu, V.[Viorel], Geana, D.[Dan]
J. Chem. Eng. Data 2004, 49, 6, 1635-1638
ABSTRACT
Isothermal (P, T, x, y) data have been measured for the binary system carbon dioxide + 1-butanol at temperatures from (293.15 to 324.15) K. The pressure range under investigation was between (0.52 and 10.09) MPa. The new experimental data are correlated with the Soave-Redlich-Kwong (SRK) equation of state coupled with the Huron-Vidal infinite dilution (HVID) mixing rules. A linear correlation of the HVID parameters with the inverse temperature is proposed by using only the data of this study. The values of HVID parameters from the linear correlation were used to predict VLE at all temperatures for which published data are available. The VLE data are reasonably well predicted for engineering purposes.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 C4H10O butan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:16
  • 59
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • OTHER
  • 59