Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities and Solubilities for Binary Systems of Carbon Dioxide + Water and Carbon Dioxide + Brine at 59 ?C and Pressures to 29 MPa

Li, Z.[Zhaowen], Dong, M.[Mingzhe], Li, S.[Shuliang], Dai, L.[Liming]
J. Chem. Eng. Data 2004, 49, 4, 1026-1031
ABSTRACT
Densities and solubilities for binary systems of carbon dioxide + water and carbon dioxide + Weyburn formation brine were measured at a temperature of 59 ?C and pressures up to 29 MPa. Density values were obtained for both the saturated and unsaturated aqueous carbon dioxide solutions at different pressures. A correlation in the literature was used to predict the solubility of carbon dioxide in the aqueous phase and the results were compared with the measured data. The measured density of aqueous carbon dioxide solutions was correlated as a function of carbon dioxide concentration and pressure. A simple method for determining the density of aqueous carbon dioxide solutions was recommended.
Compounds
# Formula Name
1 H2O water
2 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Amount concentration (molarity), mol/dm3 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • OTHER
  • 6
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Amount concentration (molarity), mol/dm3 - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Vibrating tube method
  • 29