Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Physical-Chemical Properties and Liquid-Liquid Equilibria for Binary Mixture of Diethylene Glycol Diethyl Ether with Water

Li, X.-X.[Xin-Xue], Liu, Y.-X.[Ying-Xin], Wei, X.-H.[Xiong-Hui]
J. Chem. Eng. Data 2004, 49, 4, 1043-1045
ABSTRACT
Densities, viscosities, and surface tension have been measured as a function of composition for the binary liquid mixture of diethylene glycol diethyl ether + water at 293.15 K under atmospheric pressure. Densities were determined using a capillary pycnometer. Viscosities were measured with a Ubbelohde capillary viscometer. Surface tension was measured by means of the drop-volume technique. The estimated uncertainties of the measurements were +/-0.1% for density, +/-0.3% for viscosity, and +/-0.04 mN?m-1 for surface tension. Liquid-liquid equilibrium data were also measured for the binary mixture in the temperature range from 301.15 K to 363.15 K. The compositions of both the top and bottom phases were analyzed by gas chromatography.
Compounds
# Formula Name
1 C8H18O3 diethylene glycol diethyl ether
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • DROPV:UFactor:8
  • 1
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 1
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:16
  • 1
  • POMD
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • DROPV:UFactor:8
  • 1
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:16
  • 1
  • POMD
  • 1
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • DROPV:UFactor:8
  • 16
  • POMD
  • 1
  • 2
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 28
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:16
  • 28
  • POMD
  • 1
  • 2
  • Mass fraction - 1 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • CHROM:UFactor:4
  • 11
  • POMD
  • 1
  • 2
  • Mass fraction - 1 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • CHROM:UFactor:4
  • 11