Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor-Liquid Equilibria of the Binary n-Butane (HC-600) + Difluoromethane (HFC-32), + Pentafluoroethane (HFC-125), + 1,1,1,2-Tetrafluoroethane (HFC-134a) Mixture Systems

Im, J.[Jihoon], Kim, M., Lee, B.-G., Hwayong, K.[Kim]
J. Chem. Eng. Data 2005, 50, 2, 359-363
ABSTRACT
Binary vapor liquid equilibrium data were measured for the n-butane (HC-600) + difluoromethane (HFC-32), + pentafluoroethane (HFC-125), 1,1,1,2-tetrafluoroethane (HFC-134a) systems at temperature from 313.15 K to 333.15 K. These experiments were carried out with a circulating-type apparatus with on-line gas chromatography. The experimental data were correlated well by Peng-Robinson equation of state using the Wong-Sandler mixing rules.
Compounds
# Formula Name
1 CH2F2 difluoromethane
2 C4H10 butane
3 C2HF5 pentafluoroethane
4 C2H2F4 1,1,1,2-tetrafluoroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 3
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 3
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 3
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 3
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 53
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • 53
  • POMD
  • 2
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 38
  • POMD
  • 2
  • 3
  • Mole fraction - 3 ; Gas
  • Mole fraction - 3; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:8
  • 38
  • POMD
  • 2
  • 4
  • Azeotropic composition: mole fraction - 4 ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • By X=Y
  • 3
  • POMD
  • 2
  • 4
  • Azeotropic composition: mole fraction - 4 ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • By X=Y
  • 3
  • POMD
  • 2
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 47
  • POMD
  • 2
  • 4
  • Mole fraction - 4 ; Gas
  • Mole fraction - 4; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • 47