Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement of Isobaric Vapor - Liquid Equilibria of Dimethyl Carbonate with Acetone, 2-Butanone and 2-Pentanone at 101.3 kPa and Density and Speed of Sound at 298.15 K

Pereiro, A. B.[Ana B.], Rodriguez, A., Canosa, J., Tojo, J.
J. Chem. Eng. Data 2005, 50, 2, 481-486
ABSTRACT
Densities and speeds of sound have been measured at T = 298.15 K and atmospheric pressure for acetone, 2-butanone and 2-pentanone + dimethyl carbonate over the whole composition range. Excess molar volumes and deviations in isentropic compressibility were fitted to the Redlich-Kister polynomial for the binary systems. Isobaric vapor-liquid equilibrium data for the binary systems acetone + dimethyl carbonate, 2-butanone + dimethyl carbonate, dimethyl carbonate + 2-pentanone have been experimentally determined at 101.3 kPa. The experimental data were correlated with the Wilson, NRTL and UNIQUAC equations.
Compounds
# Formula Name
1 C3H6O3 dimethyl carbonate
2 C3H6O acetone
3 C4H8O butanone
4 C5H10O pentan-2-one
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Normal boiling temperature, K ; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:32:FP
  • 1
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • FPINT:UFactor:2
  • 1
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 2
  • Normal boiling temperature, K ; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:32:FP
  • 1
  • POMD
  • 2
  • Speed of sound, m/s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • FPINT:UFactor:2
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 3
  • Normal boiling temperature, K ; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:32:FP
  • 1
  • POMD
  • 3
  • Speed of sound, m/s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • FPINT:UFactor:2
  • 1
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 4
  • Normal boiling temperature, K ; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:32:FP
  • 1
  • POMD
  • 4
  • Speed of sound, m/s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • FPINT:UFactor:2
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 2
  • 1
  • Speed of sound, m/s ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • FPINT:UFactor:2
  • 13
  • POMD
  • 2
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 34
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 13
  • POMD
  • 2
  • 1
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • RIXVDN
  • 34
  • POMD
  • 3
  • 1
  • Speed of sound, m/s ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • FPINT:UFactor:2
  • 13
  • POMD
  • 3
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 34
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 13
  • POMD
  • 3
  • 1
  • Mole fraction - 3 ; Gas
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • RIXVDN
  • 34
  • POMD
  • 4
  • 1
  • Speed of sound, m/s ; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • FPINT:UFactor:2
  • 13
  • POMD
  • 4
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 37
  • POMD
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 13
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • RIXVDN
  • 37