ABSTRACT

This paper reports the mole fraction solubilities of 9 nonpolar gases (He, Ne, Ar, Kr, Xe, CH4, C2H4, C2H6, and SF6) in dimethyl carbonate and diethyl carbonate at 278.15 K and 288.15 K, at a partial pressure of gas equal 101.33 kPa. The solubility values were fitted as a linear function of the temperature. Changes in the thermodynamic functions of solution standard (Gibbs energy, enthalpy and entropy) have been calculated from the solubilities. Finally these results have been compared with those correlated by the Scaled Particle Theory (SPT).

Compounds

#	Formula	Name
1	He	helium
2	Ne	neon
3	Ar	argon
4	Kr	krypton
5	Xe	xenon
6	CH4	methane
7	C2H6	ethane
8	F6S	sulfur hexafluoride
9	C2H4	ethene
10	C3H6O3	dimethyl carbonate
11	C5H10O3	diethyl carbonate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	10	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	3
POMD	11	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	3
POMD	10 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 1; Gas	Liquid Gas	Static method	2
POMD	10 2	Mole fraction - 2 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 2; Gas	Liquid Gas	Static method	2
POMD	10 3	Mole fraction - 3 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 3; Gas	Liquid Gas	Static method	2
POMD	10 4	Mole fraction - 4 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 4; Gas	Liquid Gas	Static method	2
POMD	10 5	Mole fraction - 5 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 5; Gas	Liquid Gas	Static method	2
POMD	6 10	Mole fraction - 6 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 6; Gas	Liquid Gas	Static method	2
POMD	7 10	Mole fraction - 7 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 7; Gas	Liquid Gas	Static method	2
POMD	9 10	Mole fraction - 9 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 9; Gas	Liquid Gas	Static method	2
POMD	10 8	Mole fraction - 8 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 8; Gas	Liquid Gas	Static method	2
POMD	11 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 1; Gas	Liquid Gas	Static method	2
POMD	11 2	Mole fraction - 2 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 2; Gas	Liquid Gas	Static method	2
POMD	11 3	Mole fraction - 3 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 3; Gas	Liquid Gas	Static method	2
POMD	11 4	Mole fraction - 4 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 4; Gas	Liquid Gas	Static method	2
POMD	11 5	Mole fraction - 5 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 5; Gas	Liquid Gas	Static method	2
POMD	6 11	Mole fraction - 6 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 6; Gas	Liquid Gas	Static method	2
POMD	7 11	Mole fraction - 7 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 7; Gas	Liquid Gas	Static method	2
POMD	9 11	Mole fraction - 9 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 9; Gas	Liquid Gas	Static method	2
POMD	11 8	Mole fraction - 8 ; Liquid	Temperature, K; Liquid	Pressure, kPa - 8; Gas	Liquid Gas	Static method	2

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities of Nonpolar Gases in Dimethyl Carbonate and Diethyl Carbonate

Terrado, E. M.[Eva M.], Pardo, J. I.[Juan I.], Urieta, J. S.[Jose S.], Mainar, A. M.[Ana M.]

ABSTRACT