ABSTRACT

Heat capacities at constant pressure of 1-chloropropane, 1-chlorobutane, 1-chloropentane, 1-chlorohexane, 1-chloroheptane, 1-chlorooctane, 1-chlorodecane and 1-bromoalkanes (1-bromoethane, 1-bromopropane, 1-bromobutane, 1-bromopentane, 1-bromohexane, 1-bromoheptane, 1-bromononane, 1-bromodecane) were measured within the temperature range from 284 K to 353 K by a differential scanning calorimeter DSC III (Setaram). These data and data previously reported for a,w -dibromoalkanes and a,w -dichloroalkanes, have been used as input for a group additivity type analysis.

Compounds

#	Formula	Name
1	C3H7Cl	1-chloropropane
2	C4H9Cl	1-chlorobutane
3	C5H11Cl	1-chloropentane
4	C6H13Cl	1-chlorohexane
5	C7H15Cl	1-chloroheptane
6	C8H17Cl	1-chlorooctane
7	C10H21Cl	1-chlorodecane
8	C2H5Br	bromoethane
9	C3H7Br	1-bromopropane
10	C4H9Br	1-bromobutane
11	C5H11Br	1-bromopentane
12	C6H13Br	1-bromohexane
13	C7H15Br	1-bromoheptane
14	C9H19Br	1-bromononane
15	C10H21Br	1-bromodecane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	13
POMD	2	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	3	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	4	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	5	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	6	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	7	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	8	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	13
POMD	9	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	24
POMD	10	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	11	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	12	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	13	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	14	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29
POMD	15	Molar heat capacity at constant pressure, J/K/mol ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	LDSC:UFactor:0.25	29

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis

Chorazewski, M.[Miroslaw], Goralski, P.[Pawel], Tkaczyk, M.[Mariola]

ABSTRACT