Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Pressures of Morpholine, Diethyl Methylmalonate, and Five Glycol Ethers at Temperatures up to 473.15 K

Lee, M. J.[Ming-Jer], Su, C.-C.[Chang-Ching], Lin, H. M.[Ho-Mu]
J. Chem. Eng. Data 2005, 50, 5, 1535-1538
ABSTRACT
Vapor pressures were measured for seven polar organic compounds including morpholine, diethyl methylmalonate, diethylene glycol diethyl ether, diethylene glycol hexyl ether, diethylene glycol dibutyl ether, ethylene glycol monobutyl ether acetate, and diethylene glycol monoethyl ether acetate at temperatures ranging from 308.15 K to 473.15 K. The measured vapor pressures of morpholine, 2-methoxyphenol, and tert-butyl alcohol agree reasonably well with literature values. The Antoine equation correlates the vapor pressure data to AADs of 0.28 % to 0.50 % for the investigated substances.
Compounds
# Formula Name
1 C4H9NO tetrahydro-1,4-oxazine
2 C8H14O4 diethyl methylpropanedioate
3 C8H18O3 diethylene glycol diethyl ether
4 C10H22O3 2-(2-hexyloxyethoxy)ethanol
5 C12H26O3 5,8,11-trioxapentadecane
6 C8H16O3 2-butoxyethyl acetate
7 C8H16O4 2-(2-ethoxyethoxy)ethyl acetate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 13
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 12
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 13
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 9
  • POMD
  • 5
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 10
  • POMD
  • 6
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 14
  • POMD
  • 7
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 13