ABSTRACT

The density, viscosity, and refractive index at (298.15, 303.15, and 308.15) K and the speed of sound at 298.15 K in binary mixtures of 1,4-dioxane with 1,2-dichlorobenzene, ethyl acetate, trichloroethylene, 2-chloroethanol, dimethyl acetamide, diethylmalonate, and 1-butanol were measured over the entire mole fraction range of the binary mixtures. Using these data, the excess molar volume, deviations in viscosity, molar refraction, speed of sound, and isentropic compressibility were calculated. The computed quantities were fitted to the Redlich-Kister equation to derive the coefficients and estimate the standard error values.

Compounds

#	Formula	Name
1	C4H8O2	1,4-dioxane
2	C6H4Cl2	1,2-dichlorobenzene
3	C4H8O2	ethyl acetate
4	C4H10O	butan-1-ol
5	C2HCl3	trichloroethene
6	C2H5ClO	1-chloro-2-hydroxyethane
7	C4H9NO	N,N-dimethylethanamide
8	C7H12O4	diethyl 1,3-propanedioate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:6	3
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	5
POMD	1	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI:UFactor:4	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	3
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:6	3
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	3
POMD	2	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:4	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:6	3
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	3
POMD	3	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:4	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:6	3
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	3
POMD	4	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:4	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:6	3
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	3
POMD	5	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:4	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:6	3
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	3
POMD	6	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:4	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:6	3
POMD	7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	3
POMD	7	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:4	1
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	8	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:6	3
POMD	8	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:4	3
POMD	8	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:4	1
POMD	8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	2 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:4	11
POMD	2 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	33
POMD	2 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:6	33
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	33
POMD	1 3	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:4	11
POMD	1 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	33
POMD	1 3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:6	33
POMD	1 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	33
POMD	4 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:4	11
POMD	4 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	33
POMD	4 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:6	33
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	33
POMD	5 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:4	11
POMD	5 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	33
POMD	5 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:6	33
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	33
POMD	6 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:4	11
POMD	6 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	33
POMD	6 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:6	33
POMD	6 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	33
POMD	1 7	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:4	11
POMD	1 7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	33
POMD	1 7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:6	33
POMD	1 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:16	33
POMD	8 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:4	11
POMD	8 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	33
POMD	8 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:6	33
POMD	8 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	33

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K

Baragi, J. G.[Jagadish G.], Aralaguppi, M. I.[Mrityunjaya I.], Aminabhavi, T. M.[Tejraj M.], Kariduraganavar, M. Y.[Mahadevappa Y.], Kulkarni, S. S.[Shrikant S.]

ABSTRACT