Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Equilibrium Surface Tensions of Benzyl Alcohol + Ethylene Glycol Mixtures

Azizian, S.[Saeid], Bashavard, N.[Nowrouz]
J. Chem. Eng. Data 2005, 50, 2, 709-712
ABSTRACT
The paper presents the properties of mixtures of benzyl alcohol and ethylene glycol at the liquid/air interface. The properties were studied by surface tension measurements carried out at as a function of the mole fraction of benzyl alcohol at temperatures between (20 and 50) C. It was shown that at constant temperature by the addition of benzyl alcohol the surface tension decreases and at constant composition by the increasing of temperature the surface tension decreases linearly. The surface entropies and enthalpies were calculated from experimental data. The surface composition of the mixture at a low concentration of benzyl alcohol was obtained from the extended Langmuir model. Values of the excess surface tension for mixtures were calculated and show a negative deviation from ideality.
Compounds
# Formula Name
1 C2H6O2 1,2-ethanediol
2 C7H8O benzenemethanol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ring tensiometer
  • 7
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 7
  • POMD
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ring tensiometer
  • 7
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 7
  • POMD
  • 2
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • Ring tensiometer
  • 91