Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of a-Carotene in Binary Solvents Formed by Some Hydrocarbons with tert-Butyl Methyl Ether and with tert-Amyl Methyl Ether

Treszczanowicz, T.[Teresa], Kasprzycka-Guttman, T.[Teresa], Treszczanowicz, A. J.[Andrzej]
J. Chem. Eng. Data 2005, 50, 3, 973-976
ABSTRACT
Experimental results are reported for the solubility of a-carotene in six binary mixed solvents formed by tert-butyl methyl ether or tert-amyl methyl ether with cyclohexane, hexane, and toluene at 293.15 K. A spectral colorimeter was used for the analysis of a-carotene concentration. The a-carotene solubility in the pure solvents increases in the order hexane < tert-butyl methyl ether < tert-amyl methyl ether < cyclohexane < toluene. The solubility data as a function of the binary solvent mole fractions were correlated by the Myers and Scott equation. Results of these measurements were used to test the predictive ability of a-carotene solubility in the binary mixed solvents using the Treszczanowicz and the Acree and Rytting models. Both models qualitatively predict the solubility of a-carotene in the above-mentioned mixed solvents.
Compounds
# Formula Name
1 C40H56 .beta.-carotene
2 C6H14 hexane
3 C7H8 toluene
4 C6H12 cyclohexane
5 C5H12O 2-methoxy-2-methylpropane
6 C6H14O 2-methoxy-2-methylbutane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 4
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 5
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 6
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Spectral colorimeter analysis
  • 1
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Spectral colorimeter analysis
  • 1
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER::sMethod:Spectral colorimeter analysis
  • 1
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER::sMethod:Spectral colorimeter analysis
  • 1
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER::sMethod:Spectral colorimeter analysis
  • 1
  • POMD
  • 4
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Spectral colorimeter analysis
  • 11
  • POMD
  • 2
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Spectral colorimeter analysis
  • 8
  • POMD
  • 3
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Spectral colorimeter analysis
  • 11
  • POMD
  • 4
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Spectral colorimeter analysis
  • 11
  • POMD
  • 2
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Spectral colorimeter analysis
  • 12
  • POMD
  • 3
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Spectral colorimeter analysis
  • 12