Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental Data on Binary and Ternary Mixtures of Perfluoromethylcyclohexane with Methane and n-Decane at 373.15 K

Gozalpour, F.[Fathollah], Danesh, A.[Ali], Todd, A. C.[Adrian C.], Tohidi, B.[Bahman]
J. Chem. Eng. Data 2005, 50, 6, 1814-1817
ABSTRACT
The phase and volumetric measurements of perfluoromethylcyclohexane + methane and perfluoromethylcyclohexane + n-decane and their ternary mixtures at 373.15 K and over a wide range of concentration are presented. The ternary mixtures are used to carry out a constant composition expansion test at 373.15 K. Measurements are made on the liquid bubble point and retrograde dew point pressures and on the single-phase density of the binary mixtures. A high-pressure high-temperature oscillating tube densitometer is used to measure the density.
Compounds
# Formula Name
1 C7F14 perfluoro(methylcyclohexane)
2 CH4 methane
3 C10H22 decane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 4
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Gas
  • Mole fraction - 1; Gas
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Ebulliometric method (Recirculating still)
  • 3
  • POMD
  • 3
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 3
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Mole fraction - 1; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Vibrating tube method
  • 1
  • POMD
  • 2
  • 3
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 2
  • POMD
  • 2
  • 3
  • 1
  • Vapor or sublimation pressure, kPa ; Gas
  • Mole fraction - 1; Gas
  • Mole fraction - 3; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Ebulliometric method (Recirculating still)
  • 2
  • POMD
  • 2
  • 3
  • 1
  • Mass density, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Mole fraction - 1; Fluid (supercritical or subcritical phases)
  • Mole fraction - 3; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Vibrating tube method
  • 4