Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Speed-of-Sound Measurements Using Spherical Resonator and Acoustic Virial Coefficients for Gaseous Pentafluoroethane (R125)

Kojima, T.[Takeshi], Okabe, K.[Kaku], Ogawa, K.[Kazuhiro], Sato, H.[Haruki]
J. Chem. Eng. Data 2004, 49, 3, 635-638
ABSTRACT
Speed-of-sound measurement with a spherical resonator is recognized as one of the most precise and reliable approaches to determine ideal-gas heat capacities and to reveal thermodynamic properties of rarefied gases. In this study, a spherical resonator was used to measure the speed of sound in gaseous pentafluoroethane, R125. Eighty speed-of-sound values were obtained along five isotherms from 277 K to 343 K and up to 600 kPa in pressure. In addition, cp values and second acoustic virial coefficients were determined at each temperature. Sample purity was 99.9% of the gas-chromatograh area fraction analyzed by the manufacturer. The expanded uncertainties with k = 2 are estimated at 11 mK in temperature, 0.31 kPa in pressure, and 72 ppm in speed of sound. The cp values reported here were compared with those from spectroscopic data. The agreement between them was within ?0.2%.
Compounds
# Formula Name
1 C2HF5 pentafluoroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Speed of sound, m/s ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • SPRES:UFactor:0.5
  • 78