ABSTRACT

The density and viscosity of binary liquid mixtures of propylene carbonate with polar and nonpolar solvents (acetone, chloroform, 1,4-dioxane benzene, toluene, and o-xylene) have been measured at 303.15 K. From density and viscosity data, the values of excess molar volume and deviations in viscosity have been determined. The excess molar volume and deviations in viscosity are negative over the entire range of composition. The density and viscosity data have been theoretically analyzed for the validity of different viscosity models.

Compounds

#	Formula	Name
1	C4H6O3	4-methyl-1,3-dioxolan-2-one
2	C3H6O	acetone
3	C4H8O2	1,4-dioxane
4	CHCl3	trichloromethane
5	C6H6	benzene
6	C7H8	toluene
7	C8H10	1,2-dimethylbenzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB::UFactor:16	1
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB::UFactor:16	1
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB::UFactor:16	1
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:16	1
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB::UFactor:16	1
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB::UFactor:16	1
POMD	7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:16	1
POMD	2 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	2 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	11
POMD	1 3	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	1 3	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	11
POMD	4 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	4 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	11
POMD	5 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	5 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	11
POMD	1 6	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	1 6	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	11
POMD	7 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	7 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	11

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Viscosity, and Excess Properties of Binary Liquid Mixtures of Propylene Carbonate with Polar and Nonpolar Solvents

Jain, P.[Pragati], Singh, M.[Mukhtar]

ABSTRACT