Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Pressure and Liquid Heat Capacity of Alkylene Carbonates

Chernyak, Y.[Yury], Clements, J. H.[John H.]
J. Chem. Eng. Data 2004, 49, 5, 1180-1184
ABSTRACT
New experimental data on vapor pressure (T = 397 to 523 K) and liquid heat capacity, Cp, (T = 283 to 393 K) of ethylene carbonate, propylene carbonate, butylene carbonate, and glycerine carbonate were developed using ebulliometery and differential scanning calorimetry techniques. These vapor pressure and liquid heat capacity data were combined with selected literature data and correlated using Wagner, Clapeyron, and polynomial-type equations.
Compounds
# Formula Name
1 C3H4O3 ethylene carbonate
2 C4H6O3 4-methyl-1,3-dioxolan-2-one
3 C5H8O3 1,2-butylene carbonate
4 C4H6O4 glycerine carbonate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Small sample (50 mg) DSC
  • 4
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 8
  • POMD
  • 2
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Small sample (50 mg) DSC
  • 10
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 19
  • POMD
  • 3
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Small sample (50 mg) DSC
  • 10
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 19
  • POMD
  • 4
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Small sample (50 mg) DSC
  • 10
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 9