Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Total Vapor Pressure Measurements for 2-Ethoxyethanol with Carbon Tetrachloride, Chloroform, and Dichloromethane at 303.15 K

Pathare, S.[Salil], Bhethanabotla, V. R.[Venkat R.], Campbell, S. W.[Scott W.]
J. Chem. Eng. Data 2004, 49, 3, 510-513
ABSTRACT
Total pressure measurements are reported for the binary mixtures of 2-ethoxyethanol with carbon tetrachloride, chloroform, and dichloromethane at 303.15 K. The data were obtained using a Van Ness type apparatus and were fitted with a modified Margules equation using Barker's method. The total pressure data are represented by the model to within an average absolute deviation of approximately 0.06 kPa. Solutions of 2-ethoxyethanol with carbon tetrachloride show positive deviations from ideality, while those of 2-ethoxyethanol with chloroform and with dichloromethane show negative deviations at low chloroalkane mole fraction and positive deviations at high chloroalkane concentration.
Compounds
# Formula Name
1 C4H10O2 2-ethoxyethan-1-ol
2 CH2Cl2 dichloromethane
3 CHCl3 trichloromethane
4 CCl4 tetrachloromethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 3
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 1
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 1
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 1
  • POMD
  • 4
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 22
  • POMD
  • 3
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 23
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 24