Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solid and Liquid Phase Equilibria in Mixtures of 1,8-Cineole with Phenol, Cyclohexanol, and an n-Alkanol

Huang, Z.[Zhongqi], Ouyang, G.[Gangfeng], Liu, F.[Faqiang], Xu, Z.[Zhuyuan], Zhang, X.[Xiliang], Zhang, W.[Weiqing]
J. Chem. Eng. Data 2003, 48, 6, 1521-1523
ABSTRACT
Solid-liquid phase diagrams have been constructed for 1,8-cineole with phenol or cyclohexanol or an n-alkanol. Solid addition compounds with the empirical formulas C10H18O?C6H5OH and C10H18O?C6H11OH were formed. Compound formation is attributed to hydrogen bonding. No solid addition compounds form in (1,8-cineole + methanol, + ethanol, + 1-propanol, or + 1-butanol).
Compounds
# Formula Name
1 C10H18O 1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane
2 C6H6O phenol
3 C6H12O cyclohexanol
4 CH4O methanol
5 C2H6O ethanol
6 C3H8O propan-1-ol
7 C4H10O butan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Solid-liquid equilibrium temperature, K ; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • Liquid
  • VISOBS
  • 1
  • POMD
  • 2
  • Solid-liquid equilibrium temperature, K ; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • Liquid
  • VISOBS
  • 1
  • POMD
  • 3
  • Solid-liquid equilibrium temperature, K ; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • Liquid
  • VISOBS
  • 1
  • POMD
  • 4
  • Solid-liquid equilibrium temperature, K ; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • Liquid
  • VISOBS
  • 1
  • POMD
  • 5
  • Solid-liquid equilibrium temperature, K ; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • Liquid
  • VISOBS
  • 1
  • POMD
  • 6
  • Solid-liquid equilibrium temperature, K ; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • Liquid
  • VISOBS
  • 1
  • POMD
  • 7
  • Solid-liquid equilibrium temperature, K ; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • Liquid
  • VISOBS
  • 1
  • POMD
  • 2
  • 1
  • Eutectic temperature, K ; Crystal - 1
  • Crystal - 1
  • Crystal of intercomponent compound 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 2
  • 1
  • Eutectic temperature, K ; Crystal of intercomponent compound 1
  • Crystal of intercomponent compound 1
  • Crystal - 2
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 2
  • 1
  • Eutectic composition: mole fraction - 2 ; Crystal - 1
  • Crystal - 1
  • Crystal of intercomponent compound 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 2
  • 1
  • Eutectic composition: mole fraction - 2 ; Crystal of intercomponent compound 1
  • Crystal of intercomponent compound 1
  • Crystal - 2
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 2
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • VISOBS
  • 8
  • POMD
  • 2
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • VISOBS
  • 7
  • POMD
  • 2
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 6
  • POMD
  • 3
  • 1
  • Eutectic temperature, K ; Crystal - 1
  • Crystal - 1
  • Crystal of intercomponent compound 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 3
  • 1
  • Eutectic temperature, K ; Crystal of intercomponent compound 1
  • Crystal of intercomponent compound 1
  • Crystal - 3
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 3
  • 1
  • Eutectic composition: mole fraction - 3 ; Crystal - 1
  • Crystal - 1
  • Crystal of intercomponent compound 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 3
  • 1
  • Eutectic composition: mole fraction - 3 ; Crystal of intercomponent compound 1
  • Crystal of intercomponent compound 1
  • Crystal - 3
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 3
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • VISOBS
  • 6
  • POMD
  • 3
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • VISOBS
  • 9
  • POMD
  • 3
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 9
  • POMD
  • 4
  • 1
  • Eutectic temperature, K ; Crystal - 4
  • Crystal - 4
  • Crystal - 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 4
  • 1
  • Eutectic composition: mole fraction - 4 ; Crystal - 4
  • Crystal - 4
  • Crystal - 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 4
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 21
  • POMD
  • 4
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 4
  • VISOBS
  • 1
  • POMD
  • 5
  • 1
  • Eutectic temperature, K ; Crystal - 5
  • Crystal - 5
  • Crystal - 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 5
  • 1
  • Eutectic composition: mole fraction - 5 ; Crystal - 5
  • Crystal - 5
  • Crystal - 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 5
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 21
  • POMD
  • 5
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 5
  • VISOBS
  • 1
  • POMD
  • 6
  • 1
  • Eutectic temperature, K ; Crystal - 6
  • Crystal - 6
  • Crystal - 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 6
  • 1
  • Eutectic composition: mole fraction - 6 ; Crystal - 6
  • Crystal - 6
  • Crystal - 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 6
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 6; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 21
  • POMD
  • 6
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 6; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 6
  • VISOBS
  • 1
  • POMD
  • 7
  • 1
  • Eutectic temperature, K ; Crystal - 7
  • Crystal - 7
  • Crystal - 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 7
  • 1
  • Eutectic composition: mole fraction - 7 ; Crystal - 7
  • Crystal - 7
  • Crystal - 1
  • Liquid
  • Air at 1 atmosphere
  • Derived from phase diagram analysis
  • 1
  • POMD
  • 7
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • VISOBS
  • 20
  • POMD
  • 7
  • 1
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 7; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 7
  • VISOBS
  • 1