Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities of p-Tolylboronic Acid, Bromobenzene and 4-Phenyltoluene in Carbon Dioxide at Elevated Pressures

Leeke, G. A.[Gary A.], Santos, R. C.[Regina C.], Seville, J.[Jonathan], Al-Duri, B.[Bushra], Kee, C. K. Y.[Connie K. Y.], Holmes, A. B.[Andrew B.]
J. Chem. Eng. Data 2004, 49, 1, 48-52
ABSTRACT
Solubility data were determined for the first time for p-tolylboronic acid, bromobenzene, and 4-phenyltoluene in carbon dioxide at (353 and 383) K and between pressures of (98 and 317) bar. Data were obtained using a cloud point apparatus fitted with an internal stirrer. The results were correlated using Chrastil's density based model.
Compounds
# Formula Name
1 C7H9BO2 p-tolylboronic acid
2 C6H5Br bromobenzene
3 C13H12 4-methylbiphenyl
4 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 4
  • 1
  • Mass concentration, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Crystal - 1
  • OTHER
  • 24
  • POMD
  • 2
  • 4
  • Mass concentration, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Liquid - 2
  • OTHER
  • 29
  • POMD
  • 4
  • 3
  • Mass concentration, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Crystal - 3
  • OTHER
  • 28