Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and Correlation of Mutual Solubilities for High Viscosity Binary Systems: Aniline + Methylcyclohexane, Phenol + Heptane, Phenol + Octane, and Glycerol + 1-Pentanol

Matsuda, H.[Hiroyuki], Fujitake, M., Ochi, K.[Kenji]
J. Chem. Eng. Data 2003, 48, 4, 1076-1080
ABSTRACT
A laser light scattering technique was used for the determination of mutual solubilities at moderate pressure (saturated vapor pressure of a mixture) in four high viscosity binary systems: aniline + methylcyclohexane, phenol + heptane, phenol + octane, and glycerol + 1-pentanol. The liquid-liquid solubility data were measured up to the upper critical solution temperature. The experimentally determined solubility data were satisfactory correlated by the NRTL equation and Tsuboka-Katayama's modification of the Wilson equation.
Compounds
# Formula Name
1 C6H7N aniline
2 C7H14 methylcyclohexane
3 C6H6O phenol
4 C7H16 heptane
5 C8H18 octane
6 C3H8O3 glycerol
7 C5H12O pentan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Upper consolute temperature, K ; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Air at 1 atmosphere
  • APPEAR
  • 1
  • POMD
  • 1
  • 2
  • Upper consolute composition: mole fraction - 1 ; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Air at 1 atmosphere
  • APPEAR
  • 1
  • POMD
  • 1
  • 2
  • Liquid-liquid equilibrium temperature, K ; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • VISOBS:UFactor:3
  • 44
  • POMD
  • 3
  • 4
  • Upper consolute temperature, K ; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Air at 1 atmosphere
  • APPEAR
  • 1
  • POMD
  • 3
  • 4
  • Upper consolute composition: mole fraction - 3 ; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Air at 1 atmosphere
  • APPEAR
  • 1
  • POMD
  • 3
  • 4
  • Liquid-liquid equilibrium temperature, K ; Liquid mixture 1
  • Mole fraction - 3; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • VISOBS:UFactor:3
  • 27
  • POMD
  • 3
  • 5
  • Upper consolute temperature, K ; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Air at 1 atmosphere
  • APPEAR
  • 1
  • POMD
  • 3
  • 5
  • Upper consolute composition: mole fraction - 3 ; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Air at 1 atmosphere
  • APPEAR
  • 1
  • POMD
  • 3
  • 5
  • Liquid-liquid equilibrium temperature, K ; Liquid mixture 1
  • Mole fraction - 3; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • VISOBS:UFactor:3
  • 17
  • POMD
  • 6
  • 7
  • Upper consolute temperature, K ; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Air at 1 atmosphere
  • APPEAR
  • 1
  • POMD
  • 6
  • 7
  • Upper consolute composition: mole fraction - 6 ; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Air at 1 atmosphere
  • OTHER
  • 1
  • POMD
  • 6
  • 7
  • Liquid-liquid equilibrium temperature, K ; Liquid mixture 1
  • Mole fraction - 6; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • VISOBS:UFactor:3
  • 22