Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Viscosity of Aqueous CO2 Solutions Measured by Dynamic Light Scattering

Uchida, T.[Tsutomu], Ohmura, R.[Ryo], Nagao, J.[Jiro], Takeya, S.[Satoshi], Ebinuma, T.[Takao], Narita, H.[Hideo]
J. Chem. Eng. Data 2003, 48, 5, 1225-1229
ABSTRACT
The viscosity of water containing dissolved CO2 at pressures up to 5 MPa was measured by a new method based on dynamic light scattering. The accuracy of this method was checked by measuring the temperature dependence of the viscosity of pure water at pressures up to 5 MPa and comparing the results to values in the literature that were determined by other methods. The discrepancy of the measured viscosity of water from the literature was 16%, which roughly equals the composite uncertainty of this method. The effect of dissolved CO2 on the viscosity was determined as functions of time, temperature, and pressure. The results indicated that the viscosity of the solution increased with increasing CO2 concentration. High viscosities were observed under conditions in which CO2 hydrates can form.
Compounds
# Formula Name
1 H2O water
2 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • OTHER
  • 40
  • POMD
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • OTHER
  • 30