Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Pressures of Hydrated Barium Chloride

Tanner, J. E.[John E.]
J. Chem. Eng. Data 2005, 50, 3, 777-779
ABSTRACT
Vapor pressures of water over the monohydrate and over the dihydrate of barium chloride were measured from 17 deg C to 72 deg C in a glass apparatus from which air had been evacuated. Equilibrium was approached from higher as well as lower pressures. Vapor pressures for the dihydrate were found to be somewhat lower than previously published values. Vapor pressures for the monohydrate confirm a few published values but are much lower than the values published later in the International Critical Tables. The enthalpies of dehydration of the dihydrate and of the monohydrate were found to be 59 +/- 2 kJamol-1and 56 +/- 3 kJamol-1, respectively.
Compounds
# Formula Name
1 BaCl2H2O barium chloride monohydrate
2 BaCl2H4O2 barium chloride dihydrate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • MANOM:UFactor:2
  • 35
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • MANOM:UFactor:4
  • 23