Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Solubilities of n-octadecane, n-nonadecane, n-eicosane, and n-tetracosane in dipropyl ether, dibutyl ether, 1-chlorobutane, and 1-chlorooctane have been measured by the synthetic method as functions of temperature from near 0 C to the melting point of the alkane. All systems exhibit small deviations from ideal solubility, positive at lower solute compositions and, for some systems, slightly negative at higher solute compositions.

Compounds

#	Formula	Name
1	C6H14O	dipropyl ether
2	C8H18O	dibutyl ether
3	C4H9Cl	1-chlorobutane
4	C8H17Cl	1-chlorooctane
5	C18H38	octadecane
6	C19H40	nonadecane
7	C20H42	eicosane
8	C24H50	tetracosane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	5	Triple point temperature, K ; Crystal 2			Crystal 2 Crystal 1 Air at 1 atmosphere	OTHER	1
POMD	5	Normal melting temperature, K ; Crystal 1			Crystal 1 Liquid Air at 1 atmosphere	VISOBS	1
POMD	6	Triple point temperature, K ; Crystal 2			Crystal 2 Crystal 1 Air at 1 atmosphere	OTHER	1
POMD	6	Triple point temperature, K ; Crystal 2			Crystal 2 Crystal 1 Air at 1 atmosphere	OTHER	1
POMD	6	Normal melting temperature, K ; Crystal 1			Crystal 1 Liquid Air at 1 atmosphere	VISOBS	1
POMD	7	Triple point temperature, K ; Crystal 2			Crystal 2 Crystal 1 Air at 1 atmosphere	OTHER	1
POMD	7	Normal melting temperature, K ; Crystal 1			Crystal 1 Liquid Air at 1 atmosphere	VISOBS	1
POMD	8	Triple point temperature, K ; Crystal 2			Crystal 2 Crystal 1 Air at 1 atmosphere	OTHER	1
POMD	8	Normal melting temperature, K ; Crystal 1			Crystal 1 Liquid Air at 1 atmosphere	VISOBS	1
POMD	1 5	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 5	VISOBS:UFactor:2	3
POMD	1 5	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 5	VISOBS:UFactor:2	23
POMD	2 5	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 5	VISOBS:UFactor:2	4
POMD	2 5	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 5	VISOBS:UFactor:2	23
POMD	1 6	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 6	VISOBS:UFactor:2	3
POMD	1 6	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 6	VISOBS:UFactor:2	31
POMD	2 6	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 6	VISOBS:UFactor:2	3
POMD	2 6	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 6	VISOBS:UFactor:2	28
POMD	1 7	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 7	VISOBS:UFactor:2	3
POMD	1 7	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 7	VISOBS:UFactor:2	29
POMD	7 2	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 7	VISOBS:UFactor:2	3
POMD	7 2	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 7	VISOBS:UFactor:2	30
POMD	1 8	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 8	VISOBS:UFactor:2	5
POMD	1 8	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 8	VISOBS:UFactor:2	33
POMD	2 8	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 8	VISOBS:UFactor:2	5
POMD	2 8	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 8	VISOBS:UFactor:2	34
POMD	3 5	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 5	VISOBS:UFactor:2	4
POMD	3 5	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 5	VISOBS:UFactor:2	23
POMD	4 5	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 5	VISOBS:UFactor:2	4
POMD	4 5	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 5	VISOBS:UFactor:2	25
POMD	3 6	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 6	VISOBS:UFactor:2	2
POMD	3 6	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 6	VISOBS:UFactor:2	27
POMD	4 6	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 6	VISOBS:UFactor:2	3
POMD	4 6	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 6	VISOBS:UFactor:2	27
POMD	3 7	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 7	VISOBS:UFactor:2	3
POMD	3 7	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 7	VISOBS:UFactor:2	28
POMD	4 7	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 7	VISOBS:UFactor:2	3
POMD	4 7	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 7	VISOBS:UFactor:2	31
POMD	3 8	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 8	VISOBS:UFactor:2	9
POMD	3 8	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 8	VISOBS:UFactor:2	68
POMD	4 8	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal 1 - 8	VISOBS:UFactor:2	4
POMD	4 8	Solid-liquid equilibrium temperature, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal 2 - 8	VISOBS:UFactor:2	34

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities of Some Long-Chain n-Alkanes in Dipropyl Ether, Dibutyl Ether, 1-Chlorobutane, and 1-Chlorooctane as Functions of Temperature

Rolinska, J.[Jolanta], Hofman, T.[Tadeusz]

ABSTRACT