Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement of Activity Coefficients of Solutes at Infinite Dilution in (Dimethyl Sulfoxide + Acetamide, or Formamide, or Urea) Using Gas Liquid Chromatography at the Temperature 298.15 K

Bai, T.-C.[Tong-Chun], Li, Q.[Qiang]
J. Chem. Eng. Data 2003, 48, 5, 1194-1201
ABSTRACT
Using gas liquid chromatography, activity coefficients of 12 solutes at infinite dilution in the stationary solvent dimethyl sulfoxide + additives (acetamide, or formamide, or urea) at the temperature 298.15 K have been measured. The effect of composition of the mixed solvents on the activity coefficients at infinite dilution and on selectivity has been discussed.
Compounds
# Formula Name
1 C2H6OS dimethyl sulfoxide
2 C7H16 heptane
3 C6H12 cyclohexane
4 C6H6 benzene
5 C4H10O diethyl ether
6 CCl4 tetrachloromethane
7 CHCl3 trichloromethane
8 CH2Cl2 dichloromethane
9 C3H6O acetone
10 C4H8O2 ethyl acetate
11 CH3NO formamide
12 C4H8O butanone
13 C4H8O tetrahydrofuran
14 C2H4O2 methyl methanoate
15 C2H5NO ethanamide
16 CH4N2O urea
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Activity coefficient - 2 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 1
  • 3
  • Activity coefficient - 3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 1
  • 4
  • Activity coefficient - 4 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 5
  • 1
  • Activity coefficient - 5 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 6
  • 1
  • Activity coefficient - 6 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 7
  • 1
  • Activity coefficient - 7 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 1
  • 8
  • Activity coefficient - 8 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 9
  • 1
  • Activity coefficient - 9 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 1
  • 10
  • Activity coefficient - 10 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 10; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 11
  • 3
  • Activity coefficient - 3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 4
  • 11
  • Activity coefficient - 4 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 5
  • 11
  • Activity coefficient - 5 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 6
  • 11
  • Activity coefficient - 6 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 7
  • 11
  • Activity coefficient - 7 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 8
  • 11
  • Activity coefficient - 8 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 11
  • 12
  • Activity coefficient - 12 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 12; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 11
  • 13
  • Activity coefficient - 13 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 13; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 1
  • 12
  • Activity coefficient - 12 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 12; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 1
  • 13
  • Activity coefficient - 13 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 13; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 1
  • 14
  • Activity coefficient - 14 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 11
  • 2
  • Activity coefficient - 2 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 9
  • 11
  • Activity coefficient - 9 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 11
  • 14
  • Activity coefficient - 14 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 11
  • 10
  • Activity coefficient - 10 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 10; Liquid
  • Liquid
  • Gas
  • CHROM:UFactor:2
  • 1
  • POMD
  • 15
  • 1
  • 2
  • Activity coefficient - 2 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 15
  • 1
  • 3
  • Activity coefficient - 3 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 15
  • 1
  • 4
  • Activity coefficient - 4 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 5
  • 15
  • 1
  • Activity coefficient - 5 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 6
  • 15
  • 1
  • Activity coefficient - 6 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 15
  • 7
  • 1
  • Activity coefficient - 7 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 15
  • 1
  • 8
  • Activity coefficient - 8 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • CHROM:UFactor:4
  • 13
  • POMD
  • 15
  • 9
  • 1
  • Activity coefficient - 9 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 15
  • 1
  • 12
  • Activity coefficient - 12 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 12; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 15
  • 1
  • 13
  • Activity coefficient - 13 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 13; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 15
  • 1
  • 14
  • Activity coefficient - 14 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 15
  • 1
  • 10
  • Activity coefficient - 10 ; Liquid
  • Mole fraction - 15; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 10; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 13
  • POMD
  • 1
  • 11
  • 2
  • Activity coefficient - 2 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 1
  • 11
  • 3
  • Activity coefficient - 3 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 1
  • 4
  • 11
  • Activity coefficient - 4 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • CHROM:UFactor:4
  • 18
  • POMD
  • 5
  • 1
  • 11
  • Activity coefficient - 5 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 6
  • 1
  • 11
  • Activity coefficient - 6 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • CHROM:UFactor:4
  • 18
  • POMD
  • 7
  • 1
  • 11
  • Activity coefficient - 7 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 1
  • 8
  • 11
  • Activity coefficient - 8 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 9
  • 1
  • 11
  • Activity coefficient - 9 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 1
  • 11
  • 12
  • Activity coefficient - 12 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 12; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 1
  • 11
  • 13
  • Activity coefficient - 13 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 13; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 1
  • 11
  • 14
  • Activity coefficient - 14 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 1
  • 11
  • 10
  • Activity coefficient - 10 ; Liquid
  • Mole fraction - 11; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 10; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 18
  • POMD
  • 16
  • 1
  • 2
  • Activity coefficient - 2 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 1
  • 3
  • Activity coefficient - 3 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 1
  • 4
  • Activity coefficient - 4 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 5
  • 1
  • Activity coefficient - 5 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 6
  • 16
  • 1
  • Activity coefficient - 6 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 7
  • 1
  • Activity coefficient - 7 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 1
  • 8
  • Activity coefficient - 8 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 9
  • 1
  • Activity coefficient - 9 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 1
  • 12
  • Activity coefficient - 12 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 12; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 1
  • 13
  • Activity coefficient - 13 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 13; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 1
  • 14
  • Activity coefficient - 14 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11
  • POMD
  • 16
  • 1
  • 10
  • Activity coefficient - 10 ; Liquid
  • Mole fraction - 16; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 10; Liquid
  • Liquid
  • CHROM:UFactor:2
  • 11