Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor-Liquid Equilibrium for Phenol + r-Methyl Benzyl Alcohol and 2-Ethoxyethanol + n-Butyl Formate

Chylinski, K.[Krzysztof], Fras, Z.[Zbigniew], Malanowski, S. K.[Stanislaw]
J. Chem. Eng. Data 2004, 49, 1, 2-6
ABSTRACT
The saturation pressure of R-methyl benzyl alcohol (358 to 398) K and n-butyl formate (313 to 359) K was measured by an ebulliometric method. The vapor-liquid equilibrium (p, T, x, y) at (353.15, 373.15, and 393.15) K was measured by the ebulliometric method for the systems phenol + R-methyl benzyl alcohol and at (333.15, 343.15, and 353.15) K for 2-ethoxyethanol + n-butyl formate. The experimental vapor pressures were correlated with the Antoine and AEOS equations, whereas VLE was correlated with AEOS equation of state.
Compounds
# Formula Name
1 C6H6O phenol
2 C8H10O 1-phenylethanol
3 C4H10O2 2-ethoxyethan-1-ol
4 C5H10O2 butyl methanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 3
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 12
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 3
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 11
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 46
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • CHROM:UFactor:2
  • 46
  • POMD
  • 3
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 48
  • POMD
  • 3
  • 4
  • Mole fraction - 3 ; Gas
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • 48