Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Total Vapor Pressure Measurements for 2-Ethoxyethanol with Methyl Acetate, Ethyl Acetate, Propyl Acetate, and Ethyl Propionate at 313.15 K and for 2-Ethoxyethanol with Methyl Formate at 308.15 K

Alderson, N. L.[Nathan L.], Bhethanabotla, V. R.[Venkat R.], Campbell, S. W.[Scott W.]
J. Chem. Eng. Data 2003, 48, 1, 92-96
ABSTRACT
Total pressure measurements are reported for the binary mixtures of 2-ethoxyethanol with methyl acetate, ethyl acetate, propyl acetate, and ethyl propionate at 313.15 K and for 2-ethoxyethanol with methyl formate at 308.15 K. The data were obtained using a Van Ness type apparatus and were fitted to the modified Margules equation (or one of its simplified cases) using Barker?s method. All mixtures show positive deviations from ideality and are represented by the model to within an average absolute deviation of approximately 0.06 kPa.
Compounds
# Formula Name
1 C2H4O2 methyl methanoate
2 C4H10O2 2-ethoxyethan-1-ol
3 C3H6O2 methyl ethanoate
4 C4H8O2 ethyl acetate
5 C5H10O2 propyl ethanoate
6 C5H10O2 ethyl propanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 1
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 4
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 1
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 1
  • POMD
  • 5
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 1
  • POMD
  • 6
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 1
  • POMD
  • 3
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 21
  • POMD
  • 2
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 22
  • POMD
  • 5
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 5; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 23
  • POMD
  • 6
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 6; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 24
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 24