Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility in Binary Solvent Mixtures: Anthracene Dissolved in Alcohol + Acetonitrile Mixtures at 298.2 K

Monarrez, C.[Cassandra], Woo, J. H.[Jee H.], Taylor, P. G.[Priscilla G.], Tran, A. M.[Anh M.], Acree, Jr., W. E.[William E.]
J. Chem. Eng. Data 2003, 48, 3, 720-722
ABSTRACT
Experimental solubilities are reported for anthracene dissolved in six binary alcohol + acetonitrile solvent mixtures at 25 oC. The alcohol cosolvents studied were methanol, ethanol, 1-pentanol, 2-pentanol, 2-methyl-1-pentanol and 4-methyl-2-pentanol. Results of these measurements are used to test a mathematical representation based upon the combined Nearly Ideal Binary Solvent (NIBS)/Redlich-Kister equation. For the six systems studied, the Combined NIBS/Redlich-Kister equation was found to mathematically describe the experimental data to within an overall average deviation of 0.7 %
Compounds
# Formula Name
1 C14H10 anthracene
2 C2H3N acetonitrile
3 CH4O methanol
4 C2H6O ethanol
5 C5H12O pentan-1-ol
6 C5H12O pentan-2-ol
7 C6H14O 2-methyl-1-pentanol
8 C6H14O 4-methyl-2-pentanol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 1
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 1
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 1
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 1
  • POMD
  • 1
  • 6
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 1
  • POMD
  • 7
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 1
  • POMD
  • 8
  • 1
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 1
  • POMD
  • 3
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 9
  • POMD
  • 4
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 9
  • POMD
  • 5
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 9
  • POMD
  • 2
  • 1
  • 6
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 9
  • POMD
  • 2
  • 7
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 9
  • POMD
  • 2
  • 8
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • OTHER
  • 9