ABSTRACT

Densities, viscosities, and refractive indices at (298.15, 303.15, and 308.15) K, and the speed of sound at 298.15 K, are presented as a function of mixture composition for the binary mixtures of ethyl chloroacetate + cyclohexanone, + chlorobenzene, + bromobenzene, or + benzyl alcohol. Using these data, excess molar volume and deviations in viscosity, molar refraction, and speed of sound have been calculated. These results have been correlated with the Redlich and Kister polynomial equation to derive the coefficients and standard errors. Variations in the calculated excess quantities have been studied for mixtures of ethyl chloroacetate with component liquids.

Compounds

#	Formula	Name
1	C4H7ClO2	ethyl chloroethanoate
2	C6H10O	cyclohexanone
3	C6H5Cl	chlorobenzene
4	C6H5Br	bromobenzene
5	C7H8O	benzenemethanol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:2	3
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	3
POMD	1	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI:UFactor:2	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:8	3
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:2	3
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	2	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:2	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:8	3
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:2	3
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	3	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:2	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:2	3
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	4	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:2	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:4	3
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:2	3
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	5	Speed of sound, m/s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	LVPAI::UFactor:2	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:8	3
POMD	1 2	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:2	11
POMD	1 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	1 2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:2	33
POMD	1 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:8	33
POMD	1 3	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:2	11
POMD	1 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	1 3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:2	33
POMD	1 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	33
POMD	1 4	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:2	11
POMD	1 4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	1 4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:2	33
POMD	1 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:4	33
POMD	5 1	Speed of sound, m/s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	LVPAI:UFactor:2	11
POMD	5 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	5 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:2	32
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:8	33

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Ethyl Chloroacetate + Cyclohexanone, + Chlorobenzene, + Bromobenzene, or + Benzyl Alcohol at (298.15, 303.15, and 308.15) K

Nayak, J.N.[Jyoti], Aralaguppi, M. I.[Mrityunjaya I.], Aminabhavi, T. M.[Tejraj M.]

ABSTRACT