Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurements, Correlations, and Predictions of Viscosities for the Ternary Mixture (2-Butanol + Hexane + 1-Chlorobutane) at 298.15 K and 313.15 K

Dominguez, M., Langa, E., Mainar, A. M.[Ana M.], Santafe, J., Urieta, J. S.[Jose S.]
J. Chem. Eng. Data 2003, 48, 2, 302-307
ABSTRACT
Viscosities of the ternary mixture (2-butanol + hexane + 1-chlorobutane) at 298.15 K and 313.15 K have been measured at atmospheric pressure. Viscosity deviations for the ternary system were fitted to Cibulka's equation. To correlate experimental data of the ternary system, extended Nissan-Grunberg and McAllister equations have been used and their parameters have been calculated. The "viscosity-thermodynamic" model (UNIMOD) has been applied first to correlate experimental data for the binary mixtures and then to predict the viscosity for the ternary system. The group-contribution thermodynamic viscosity model (GC-UNIMOD) and the group contribution method proposed by Wu have been applied to predict the viscosity for the binary and ternary systems.
Compounds
# Formula Name
1 C4H10O butan-2-ol
2 C6H14 hexane
3 C4H9Cl 1-chlorobutane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 2
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 2
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 2
  • POMD
  • 1
  • 3
  • 2
  • Kinematic viscosity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 92