2 0 2019 bad gar 0 journal Original Badajoz, P. S.[Pedro Susial] Garcia-Vera, D.[Diego] Marrero-Perez, A.[Anibal] Padron-Guerra, N.[Nieves] Mujica-Gonzalez, T.[Tatiana] J. Chem. Eng. Data 2019 2020-09-29 Measurement of VLE Data by Using an Experimental Installation with Automatic Control: Modeling of Binary Systems of Methyl Acetate or Ethyl Acetate with n-Heptane or 2,2,4-Trimethylpentane at Both 0.1 and 1.5 MPa The excess volume of binary mixtures and the isobaric vapor-liquid equilibrium (VLE) data at high pressure have been determined. The VLE for Methyl Acetate + n-Heptane or 2,2,4-Trimethylpentane and Ethyl Acetate + n-Heptane or 2,2,4-Trimethylpentane at several pressures were obtained experimentally using a stainless steel ebulliometer. The experimental data at 0.1 MPa were verified by using the point-to-point test. The high pressure data were verified by employing the - approximation. The equations of state (EOS) of Peng-Robinson-Stryjek-Vera, with both quadratic or Wong-Sandler mixing rules, and the PC-SAFT were applied for modelling purposes. It has been verified that the azeotropic point in the binary mixtures of this work was eliminated by increasing the pressure. Vapor-liquid equilibrium n-Heptane 2 2 4-Trimethylpentane Ester Azeotrope 10.1021/acs.jced.9b00668 12 64 5591-5608 1 InChI=1S/C3H6O2/c1-3(4)5-2/h1-2H3 KXKVLQRXCPHEJC-UHFFFAOYSA-N methyl ethanoate acetic acid, methyl ester ethanoic acid, methyl ester methyl acetate C3H6O2 1 Commercial source 1 99.8 3 Stated by supplier 2 InChI=1S/C4H8O2/c1-3-6-4(2)5/h3H2,1-2H3 XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate ethyl ethanoate C4H8O2 1 Commercial source 1 99.9 3 Stated by supplier 3 InChI=1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3 IMNFDUFMRHMDMM-UHFFFAOYSA-N heptane n-heptane C7H16 1 Commercial source 1 99 2 Stated by supplier 4 InChI=1S/C8H18/c1-7(2)6-8(3,4)5/h7H,6H2,1-5H3 NHTMVDHEPJAVLT-UHFFFAOYSA-N 2,2,4-trimethylpentane isooctane C8H18 1 Commercial source 1 99.5 3 Stated by supplier 1 1 1 Principal objective of the work EP EP 8/26/2019 1

Refractive index (Na D-line) Standard Abbe refractometry

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Temperature, K Liquid 2 Pressure, kPa Liquid 1 298.15 5 2 101.3 4 1 1.35875 6 1 0.00035 2 1 1 Principal objective of the work EP EP 8/26/2019 1

Mass density, kg/m3 Vibrating tube method

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Pressure, kPa Liquid 2 Temperature, K Liquid 1 101.3 4 2 298.15 5 1 927.1 4 1 0.2 3 1 1 Principal objective of the work EP EP 8/26/2019 1

Vapor or sublimation pressure, kPa Ebulliometric method (Recirculating still)

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Temperature, K Liquid 1 436.08 5 1 1500 2 1 3 1 329.99 5 1 100 1 1 3 4 2 1 Principal objective of the work EP EP 8/26/2019 1

Refractive index (Na D-line) Standard Abbe refractometry

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Temperature, K Liquid 2 Pressure, kPa Liquid 1 298.15 5 2 101.3 4 1 1.36981 6 1 0.00035 5 2 1 Principal objective of the work EP EP 8/26/2019 1

Mass density, kg/m3 Vibrating tube method

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Pressure, kPa Liquid 2 Temperature, K Liquid 1 101.3 4 2 298.15 5 1 894.4 4 1 0.2 6 2 1 Principal objective of the work EP EP 8/26/2019 1

Vapor or sublimation pressure, kPa Ebulliometric method (Recirculating still)

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Temperature, K Liquid 1 462.75 5 1 1500 2 1 3 1 350.19 5 1 100 1 1 3 7 3 1 Principal objective of the work EP EP 8/26/2019 1

Refractive index (Na D-line) Standard Abbe refractometry

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Temperature, K Liquid 2 Pressure, kPa Liquid 1 298.15 5 2 101.3 4 1 1.38527 6 1 0.0004 8 3 1 Principal objective of the work EP EP 8/26/2019 1

Mass density, kg/m3 Vibrating tube method

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Pressure, kPa Liquid 2 Temperature, K Liquid 1 101.3 4 2 298.15 5 1 679.7 4 1 0.3 9 3 1 Principal objective of the work EP EP 8/26/2019 1

Vapor or sublimation pressure, kPa Ebulliometric method (Recirculating still)

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Temperature, K Liquid 1 498.65 5 1 1500 2 1 15 10 4 1 Principal objective of the work EP EP 8/26/2019 1

Refractive index (Na D-line) Standard Abbe refractometry

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Temperature, K Liquid 2 Pressure, kPa Liquid 1 298.15 5 2 101.3 4 1 1.38905 6 1 0.00036 11 4 1 Principal objective of the work EP EP 8/26/2019 1

Mass density, kg/m3 Vibrating tube method

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Pressure, kPa Liquid 2 Temperature, K Liquid 1 101.3 4 2 298.15 5 1 687.8 4 1 0.3 12 4 1 Principal objective of the work EP EP 8/26/2019 1

Vapor or sublimation pressure, kPa Ebulliometric method (Recirculating still)

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Temperature, K Liquid 1 371.91 5 1 100 1 1 3 1 504.65 5 1 1500 2 1 3 13 1 1 3 1 Principal objective of the work EP EP 8/26/2019 1

Mass density, kg/m3 Vibrating tube method

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Pressure, kPa Liquid 101.3 4 2 Temperature, K Liquid 298.15 5 1 Mole fraction 1 Liquid 1 0 5 1 679.7 4 1 0.3 1 0.0579 3 1 685.5 4 1 0.3 1 0.0789 3 1 687.8 4 1 0.3 1 0.0926 3 1 689.7 4 1 0.3 1 0.1276 4 1 694.1 4 1 0.3 1 0.1562 4 1 697.4 4 1 0.3 1 0.1662 4 1 698.8 4 1 0.3 1 0.1998 4 1 703.2 4 1 0.3 1 0.1998 4 1 703.2 4 1 0.3 1 0.2413 4 1 709.3 4 1 0.3 1 0.2652 4 1 712.7 4 1 0.3 1 0.2914 4 1 716.8 4 1 0.3 1 0.3583 4 1 728.4 4 1 0.3 1 0.4171 4 1 739 4 1 0.3 1 0.43 4 1 741.6 4 1 0.3 1 0.4682 4 1 749.3 4 1 0.3 1 0.506 4 1 757.3 4 1 0.3 1 0.5357 4 1 764 4 1 0.3 1 0.584 4 1 775.6 4 1 0.3 1 0.6338 4 1 788.4 4 1 0.3 1 0.715 4 1 811.7 4 1 0.2 1 0.7194 4 1 813 4 1 0.2 1 0.7256 4 1 814.9 4 1 0.2 1 0.7698 4 1 829 4 1 0.2 1 0.7698 4 1 829 4 1 0.2 1 0.7996 4 1 839.2 4 1 0.2 1 0.8104 4 1 843.3 4 1 0.2 1 0.8285 4 1 850.2 4 1 0.2 1 0.8537 4 1 859.8 4 1 0.2 1 0.8558 4 1 860.5 4 1 0.2 1 0.8898 4 1 874.1 4 1 0.2 1 0.901 4 1 879.1 4 1 0.2 1 0.9172 4 1 885.8 4 1 0.2 1 0.9284 4 1 890.8 4 1 0.2 1 0.9598 4 1 905.6 4 1 0.2 1 0.9631 4 1 907.4 4 1 0.2 1 0.9735 4 1 912.8 4 1 0.2 1 1 5 1 927.1 4 1 0.2 14 1 1 3 1 Principal objective of the work EP EP 8/26/2019 1

Mole fraction Density calibration data 1

Gas Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Gas Liquid 1 Pressure, kPa Gas 1500 2 1 Mole fraction 1 Liquid 1 0 4 1 0 4 1 0.019 2 1 0.036 2 1 0.01 1 0.035 2 1 0.083 2 1 0.013 1 0.05 2 1 0.13 3 1 0.011 1 0.076 2 1 0.183 3 1 0.01 1 0.093 2 1 0.225 3 1 0.01 1 0.119 3 1 0.278 3 1 0.01 1 0.148 3 1 0.333 3 1 0.01 1 0.175 3 1 0.378 3 1 0.009 1 0.217 3 1 0.434 3 1 0.009 1 0.288 3 1 0.528 3 1 0.01 1 0.316 3 1 0.561 3 1 0.009 1 0.372 3 1 0.617 3 1 0.008 1 0.401 3 1 0.644 3 1 0.007 1 0.428 3 1 0.665 3 1 0.007 1 0.491 3 1 0.709 3 1 0.006 1 0.521 3 1 0.727 3 1 0.006 1 0.558 3 1 0.743 3 1 0.006 1 0.596 3 1 0.763 3 1 0.006 1 0.624 3 1 0.778 3 1 0.006 1 0.646 3 1 0.792 3 1 0.005 1 0.68 3 1 0.807 3 1 0.005 1 0.738 3 1 0.838 3 1 0.005 1 0.769 3 1 0.852 3 1 0.005 1 0.796 3 1 0.868 3 1 0.005 1 0.827 3 1 0.883 3 1 0.005 1 0.855 3 1 0.898 3 1 0.005 1 0.885 3 1 0.913 3 1 0.005 1 0.91 3 1 0.93 3 1 0.005 1 0.936 3 1 0.949 3 1 0.005 1 0.959 3 1 0.966 3 1 0.005 1 0.977 3 1 0.981 3 1 0.005 1 0.992 3 1 0.994 3 1 0.005 1 1 4 1 1 4 15 1 1 3 1 Principal objective of the work EP EP 8/26/2019 1

Boiling temperature at pressure P, K Ebulliometric method (Recirculating still)

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Pressure, kPa Liquid 1500 2 1 Mole fraction 1 Liquid 1 0 4 1 498.65 5 1 0.22 1 0.019 2 1 495.85 5 1 0.67 1 0.035 2 1 493.05 5 1 0.71 1 0.05 2 1 490.65 5 1 0.59 1 0.076 2 1 487.35 5 1 0.6 1 0.093 2 1 484.55 5 1 0.6 1 0.119 3 1 481.25 5 1 0.57 1 0.148 3 1 477.25 5 1 0.55 1 0.175 3 1 474.25 5 1 0.49 1 0.217 3 1 469.7 5 1 0.46 1 0.288 3 1 462.69 5 1 0.44 1 0.316 3 1 460.28 5 1 0.39 1 0.372 3 1 455.89 5 1 0.36 1 0.401 3 1 454.18 5 1 0.32 1 0.428 3 1 452.6 5 1 0.3 1 0.491 3 1 449.35 5 1 0.29 1 0.521 3 1 448.01 5 1 0.26 1 0.558 3 1 446.83 5 1 0.25 1 0.596 3 1 445.54 5 1 0.26 1 0.624 3 1 444.56 5 1 0.26 1 0.646 3 1 443.62 5 1 0.26 1 0.68 3 1 442.61 5 1 0.25 1 0.738 3 1 440.9 5 1 0.24 1 0.769 3 1 440.31 5 1 0.23 1 0.796 3 1 439.62 5 1 0.24 1 0.827 3 1 438.81 5 1 0.23 1 0.855 3 1 438.34 5 1 0.22 1 0.885 3 1 437.83 5 1 0.23 1 0.91 3 1 437.29 5 1 0.22 1 0.936 3 1 436.97 5 1 0.22 1 0.959 3 1 436.56 5 1 0.23 1 0.977 3 1 436.25 5 1 0.22 1 0.992 3 1 436.17 5 1 0.22 1 1 4 1 436.08 5 1 0.21 16 2 1 3 1 Principal objective of the work EP EP 8/26/2019 1

Mass density, kg/m3 Vibrating tube method

Mole fraction Density calibration data 2

Gas Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Gas Liquid 1 Pressure, kPa Gas 1500 2 1 Mole fraction 2 Liquid 1 0 4 1 0 4 1 0.007 1 1 0.013 2 1 0.009 1 0.011 2 1 0.025 2 1 0.009 1 0.025 2 1 0.05 2 1 0.009 1 0.045 2 1 0.092 2 1 0.009 1 0.071 2 1 0.137 3 1 0.009 1 0.127 3 1 0.25 3 1 0.008 1 0.185 3 1 0.319 3 1 0.008 1 0.226 3 1 0.364 3 1 0.008 1 0.292 3 1 0.434 3 1 0.009 1 0.322 3 1 0.463 3 1 0.009 1 0.352 3 1 0.492 3 1 0.009 1 0.419 3 1 0.551 3 1 0.008 1 0.484 3 1 0.602 3 1 0.008 1 0.528 3 1 0.636 3 1 0.007 1 0.576 3 1 0.672 3 1 0.007 1 0.599 3 1 0.69 3 1 0.007 1 0.628 3 1 0.708 3 1 0.006 1 0.649 3 1 0.724 3 1 0.006 1 0.704 3 1 0.764 3 1 0.006 1 0.729 3 1 0.782 3 1 0.006 1 0.755 3 1 0.801 3 1 0.006 1 0.78 3 1 0.817 3 1 0.006 1 0.804 3 1 0.836 3 1 0.006 1 0.884 3 1 0.895 3 1 0.005 1 0.937 3 1 0.943 3 1 0.005 1 0.958 3 1 0.962 3 1 0.005 1 0.991 3 1 0.992 3 1 0.005 1 1 4 1 1 4 18 2 1 3 1 Principal objective of the work EP EP 8/26/2019 1

Boiling temperature at pressure P, K Ebulliometric method (Recirculating still)

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Pressure, kPa Liquid 1500 2 1 Mole fraction 2 Liquid 1 0 4 1 498.65 5 1 0.22 1 0.007 1 1 497.95 5 1 0.42 1 0.011 2 1 497.65 5 1 0.43 1 0.025 2 1 496.35 5 1 0.41 1 0.045 2 1 494.65 5 1 0.4 1 0.071 2 1 492.45 5 1 0.38 1 0.127 3 1 488.25 5 1 0.35 1 0.185 3 1 484.65 5 1 0.33 1 0.226 3 1 482.25 5 1 0.31 1 0.292 3 1 478.75 5 1 0.3 1 0.322 3 1 477.45 5 1 0.29 1 0.352 3 1 475.95 5 1 0.28 1 0.419 3 1 473 5 1 0.27 1 0.484 3 1 470.71 5 1 0.26 1 0.528 3 1 469.07 5 1 0.25 1 0.576 3 1 467.62 5 1 0.25 1 0.599 3 1 466.85 5 1 0.24 1 0.628 3 1 466.24 5 1 0.23 1 0.649 3 1 465.92 5 1 0.23 1 0.704 3 1 464.73 5 1 0.23 1 0.729 3 1 464.37 5 1 0.22 1 0.755 3 1 463.98 5 1 0.22 1 0.78 3 1 463.77 5 1 0.22 1 0.804 3 1 463.56 5 1 0.22 1 0.884 3 1 463.06 5 1 0.22 1 0.937 3 1 462.88 5 1 0.21 1 0.958 3 1 462.82 5 1 0.21 1 0.991 3 1 462.77 5 1 0.21 1 1 4 1 462.75 5 1 0.21 19 1 1 4 1 Principal objective of the work EP EP 8/26/2019 1

Mass density, kg/m3 Vibrating tube method

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid 1 Pressure, kPa Liquid 101.3 4 2 Temperature, K Liquid 298.15 5 1 Mole fraction 1 Liquid 1 0 5 1 687.8 4 1 0.3 1 0.0646 3 1 693.5 4 1 0.3 1 0.0822 3 1 695.3 4 1 0.3 1 0.0859 3 1 695.7 4 1 0.3 1 0.0992 3 1 697 4 1 0.3 1 0.1566 4 1 703.6 4 1 0.3 1 0.1941 4 1 707.9 4 1 0.3 1 0.208 4 1 709.7 4 1 0.3 1 0.224 4 1 711.7 4 1 0.3 1 0.2636 4 1 717.1 4 1 0.3 1 0.2688 4 1 717.7 4 1 0.3 1 0.2957 4 1 721.6 4 1 0.3 1 0.3211 4 1 725.4 4 1 0.3 1 0.3319 4 1 727 4 1 0.3 1 0.3956 4 1 737.4 4 1 0.3 1 0.5015 4 1 757.3 4 1 0.2 1 0.578 4 1 774 4 1 0.2 1 0.5792 4 1 774.3 4 1 0.2 1 0.6528 4 1 792.8 4 1 0.2 1 0.6958 4 1 804.5 4 1 0.2 1 0.7268 4 1 813.9 4 1 0.2 1 0.7611 4 1 824.8 4 1 0.2 1 0.7834 4 1 832.2 4 1 0.2 1 0.8161 4 1 843.6 4 1 0.2 1 0.8466 4 1 855.3 4 1 0.2 1 0.848 4 1 855.8 4 1 0.2 1 0.8628 4 1 861.6 4 1 0.2 1 0.8632 4 1 861.9 4 1 0.2 1 0.8889 4 1 872.5 4 1 0.2 1 0.9179 4 1 885.5 4 1 0.2 1 0.9388 4 1 895.1 4 1 0.2 1 0.9406 4 1 895.7 4 1 0.2 1 0.9456 4 1 898.3 4 1 0.2 1 0.9574 4 1 904.3 4 1 0.2 1 1 5 1 927.1 4 1 0.2 20 1 1 4 1 Principal objective of the work EP EP 8/26/2019 1

Mole fraction Density calibration data 1

Gas Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Gas Liquid 1 Pressure, kPa Gas 2 Mole fraction 1 Liquid 1 100 1 2 0 4 1 0 4 1 100 1 2 0.039 2 1 0.274 3 1 0.024 1 100 1 2 0.064 2 1 0.372 3 1 0.015 1 100 1 2 0.089 2 1 0.448 3 1 0.014 1 100 1 2 0.113 3 1 0.519 3 1 0.012 1 100 1 2 0.141 3 1 0.568 3 1 0.01 1 100 1 2 0.176 3 1 0.615 3 1 0.009 1 100 1 2 0.199 3 1 0.647 3 1 0.008 1 100 1 2 0.231 3 1 0.678 3 1 0.007 1 100 1 2 0.256 3 1 0.698 3 1 0.007 1 100 1 2 0.287 3 1 0.719 3 1 0.006 1 100 1 2 0.321 3 1 0.739 3 1 0.006 1 100 1 2 0.362 3 1 0.756 3 1 0.006 1 100 1 2 0.387 3 1 0.767 3 1 0.005 1 100 1 2 0.417 3 1 0.778 3 1 0.005 1 100 1 2 0.436 3 1 0.786 3 1 0.005 1 100 1 2 0.457 3 1 0.794 3 1 0.005 1 100 1 2 0.501 3 1 0.801 3 1 0.005 1 100 1 2 0.519 3 1 0.81 3 1 0.005 1 100 1 2 0.571 3 1 0.822 3 1 0.005 1 100 1 2 0.618 3 1 0.834 3 1 0.005 1 100 1 2 0.66 3 1 0.845 3 1 0.005 1 100 1 2 0.694 3 1 0.853 3 1 0.005 1 100 1 2 0.734 3 1 0.862 3 1 0.005 1 100 1 2 0.767 3 1 0.87 3 1 0.005 1 100 1 2 0.794 3 1 0.879 3 1 0.005 1 100 1 2 0.827 3 1 0.889 3 1 0.005 1 100 1 2 0.853 3 1 0.899 3 1 0.005 1 100 1 2 0.883 3 1 0.911 3 1 0.005 1 100 1 2 0.906 3 1 0.924 3 1 0.005 1 100 1 2 0.93 3 1 0.937 3 1 0.005 1 100 1 2 0.946 3 1 0.948 3 1 0.005 1 100 1 2 0.957 3 1 0.958 3 1 0.005 1 100 1 2 0.968 3 1 0.967 3 1 0.006 1 100 1 2 0.983 3 1 0.982 3 1 0.006 1 100 1 2 0.995 3 1 0.994 3 1 0.006 1 100 1 2 1 4 1 1 4 1 1500 2 2 0 4 1 0 4 1 1500 2 2 0.026 2 1 0.084 2 1 0.012 1 1500 2 2 0.077 2 1 0.219 3 1 0.011 1 1500 2 2 0.112 3 1 0.296 3 1 0.01 1 1500 2 2 0.139 3 1 0.344 3 1 0.009 1 1500 2 2 0.173 3 1 0.402 3 1 0.009 1 1500 2 2 0.201 3 1 0.44 3 1 0.009 1 1500 2 2 0.228 3 1 0.478 3 1 0.01 1 1500 2 2 0.253 3 1 0.515 3 1 0.009 1 1500 2 2 0.305 3 1 0.575 3 1 0.008 1 1500 2 2 0.359 3 1 0.624 3 1 0.008 1 1500 2 2 0.385 3 1 0.647 3 1 0.007 1 1500 2 2 0.412 3 1 0.67 3 1 0.007 1 1500 2 2 0.462 3 1 0.707 3 1 0.006 1 1500 2 2 0.485 3 1 0.721 3 1 0.006 1 1500 2 2 0.51 3 1 0.735 3 1 0.006 1 1500 2 2 0.529 3 1 0.745 3 1 0.006 1 1500 2 2 0.555 3 1 0.756 3 1 0.006 1 1500 2 2 0.578 3 1 0.77 3 1 0.006 1 1500 2 2 0.614 3 1 0.784 3 1 0.005 1 1500 2 2 0.638 3 1 0.798 3 1 0.005 1 1500 2 2 0.663 3 1 0.811 3 1 0.005 1 1500 2 2 0.692 3 1 0.826 3 1 0.005 1 1500 2 2 0.724 3 1 0.839 3 1 0.005 1 1500 2 2 0.752 3 1 0.854 3 1 0.005 1 1500 2 2 0.785 3 1 0.869 3 1 0.005 1 1500 2 2 0.825 3 1 0.892 3 1 0.005 1 1500 2 2 0.864 3 1 0.907 3 1 0.005 1 1500 2 2 0.896 3 1 0.927 3 1 0.005 1 1500 2 2 0.918 3 1 0.942 3 1 0.005 1 1500 2 2 0.948 3 1 0.959 3 1 0.005 1 1500 2 2 0.984 3 1 0.988 3 1 0.005 1 1500 2 2 0.995 3 1 0.996 3 1 0.004 1 1500 2 2 1 4 1 1 4 21 1 1 4 1 Principal objective of the work EP EP 8/26/2019 1

Boiling temperature at pressure P, K Ebulliometric method (Recirculating still)

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Mole fraction 1 Liquid 2 Pressure, kPa Liquid 1 0 4 2 100 1 1 371.91 5 1 0.34 1 0.039 2 2 100 1 1 362.72 5 1 0.92 1 0.064 2 2 100 1 1 358.41 5 1 0.71 1 0.089 2 2 100 1 1 354.98 5 1 0.65 1 0.113 3 2 100 1 1 351.68 5 1 0.57 1 0.141 3 2 100 1 1 349.05 5 1 0.48 1 0.176 3 2 100 1 1 346.17 5 1 0.46 1 0.199 3 2 100 1 1 344.54 5 1 0.43 1 0.231 3 2 100 1 1 342.49 5 1 0.41 1 0.256 3 2 100 1 1 341.16 5 1 0.38 1 0.287 3 2 100 1 1 339.82 5 1 0.36 1 0.321 3 2 100 1 1 338.45 5 1 0.35 1 0.362 3 2 100 1 1 337.32 5 1 0.34 1 0.387 3 2 100 1 1 336.53 5 1 0.34 1 0.417 3 2 100 1 1 335.8 5 1 0.33 1 0.436 3 2 100 1 1 335.33 5 1 0.33 1 0.457 3 2 100 1 1 334.85 5 1 0.32 1 0.501 3 2 100 1 1 334.28 5 1 0.32 1 0.519 3 2 100 1 1 333.77 5 1 0.32 1 0.571 3 2 100 1 1 333.06 5 1 0.31 1 0.618 3 2 100 1 1 332.41 5 1 0.31 1 0.66 3 2 100 1 1 331.85 5 1 0.31 1 0.694 3 2 100 1 1 331.5 5 1 0.31 1 0.734 3 2 100 1 1 331.1 5 1 0.31 1 0.767 3 2 100 1 1 330.79 5 1 0.31 1 0.794 3 2 100 1 1 330.47 5 1 0.3 1 0.827 3 2 100 1 1 330.2 5 1 0.3 1 0.853 3 2 100 1 1 330.06 5 1 0.3 1 0.883 3 2 100 1 1 329.84 5 1 0.3 1 0.906 3 2 100 1 1 329.73 5 1 0.3 1 0.93 3 2 100 1 1 329.61 5 1 0.3 1 0.946 3 2 100 1 1 329.54 5 1 0.3 1 0.957 3 2 100 1 1 329.52 5 1 0.3 1 0.968 3 2 100 1 1 329.57 5 1 0.3 1 0.983 3 2 100 1 1 329.71 5 1 0.3 1 0.995 3 2 100 1 1 329.89 5 1 0.3 1 1 4 2 100 1 1 329.99 5 1 0.29 1 0 4 2 1500 2 1 504.65 5 1 0.62 1 0.026 2 2 1500 2 1 499.45 5 1 0.95 1 0.077 2 2 1500 2 1 490.75 5 1 0.9 1 0.112 3 2 1500 2 1 485.75 5 1 0.84 1 0.139 3 2 1500 2 1 482.05 5 1 0.8 1 0.173 3 2 1500 2 1 477.95 5 1 0.77 1 0.201 3 2 1500 2 1 474.85 5 1 0.76 1 0.228 3 2 1500 2 1 471.76 5 1 0.76 1 0.253 3 2 1500 2 1 468.88 5 1 0.71 1 0.305 3 2 1500 2 1 464.2 5 1 0.68 1 0.359 3 2 1500 2 1 459.75 5 1 0.66 1 0.385 3 2 1500 2 1 457.78 5 1 0.63 1 0.412 3 2 1500 2 1 456.09 5 1 0.62 1 0.462 3 2 1500 2 1 452.91 5 1 0.61 1 0.485 3 2 1500 2 1 451.6 5 1 0.59 1 0.51 3 2 1500 2 1 450.36 5 1 0.58 1 0.529 3 2 1500 2 1 449.62 5 1 0.57 1 0.555 3 2 1500 2 1 448.73 5 1 0.56 1 0.578 3 2 1500 2 1 447.79 5 1 0.56 1 0.614 3 2 1500 2 1 446.38 5 1 0.56 1 0.638 3 2 1500 2 1 445.63 5 1 0.56 1 0.663 3 2 1500 2 1 444.45 5 1 0.55 1 0.692 3 2 1500 2 1 443.54 5 1 0.54 1 0.724 3 2 1500 2 1 442.73 5 1 0.54 1 0.752 3 2 1500 2 1 441.92 5 1 0.53 1 0.785 3 2 1500 2 1 441.01 5 1 0.53 1 0.825 3 2 1500 2 1 439.94 5 1 0.53 1 0.864 3 2 1500 2 1 438.8 5 1 0.53 1 0.896 3 2 1500 2 1 437.97 5 1 0.52 1 0.918 3 2 1500 2 1 437.59 5 1 0.52 1 0.948 3 2 1500 2 1 436.85 5 1 0.51 1 0.984 3 2 1500 2 1 436.34 5 1 0.51 1 0.995 3 2 1500 2 1 436.17 5 1 0.51 1 1 4 2 1500 2 1 436.08 5 1 0.5 22 2 1 4 1 Principal objective of the work EP EP 8/26/2019 1

Mass density, kg/m3 Vibrating tube method

Mole fraction Density calibration data 2

Gas Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Gas Liquid 1 Pressure, kPa Gas 2 Mole fraction 2 Liquid 1 100 1 2 0 4 1 0 4 1 100 1 2 0.005 1 1 0.024 2 1 0.015 1 100 1 2 0.024 2 1 0.093 2 1 0.015 1 100 1 2 0.047 2 1 0.17 3 1 0.012 1 100 1 2 0.075 2 1 0.237 3 1 0.011 1 100 1 2 0.101 3 1 0.298 3 1 0.01 1 100 1 2 0.141 3 1 0.363 3 1 0.009 1 100 1 2 0.198 3 1 0.436 3 1 0.009 1 100 1 2 0.284 3 1 0.525 3 1 0.009 1 100 1 2 0.315 3 1 0.553 3 1 0.008 1 100 1 2 0.348 3 1 0.575 3 1 0.008 1 100 1 2 0.385 3 1 0.603 3 1 0.007 1 100 1 2 0.422 3 1 0.625 3 1 0.007 1 100 1 2 0.444 3 1 0.637 3 1 0.007 1 100 1 2 0.469 3 1 0.65 3 1 0.007 1 100 1 2 0.509 3 1 0.669 3 1 0.007 1 100 1 2 0.547 3 1 0.688 3 1 0.006 1 100 1 2 0.619 3 1 0.726 3 1 0.006 1 100 1 2 0.661 3 1 0.742 3 1 0.006 1 100 1 2 0.686 3 1 0.759 3 1 0.006 1 100 1 2 0.728 3 1 0.779 3 1 0.006 1 100 1 2 0.762 3 1 0.8 3 1 0.005 1 100 1 2 0.792 3 1 0.816 3 1 0.005 1 100 1 2 0.816 3 1 0.831 3 1 0.005 1 100 1 2 0.839 3 1 0.843 3 1 0.005 1 100 1 2 0.867 3 1 0.863 3 1 0.005 1 100 1 2 0.895 3 1 0.885 3 1 0.006 1 100 1 2 0.944 3 1 0.931 3 1 0.006 1 100 1 2 0.971 3 1 0.962 3 1 0.006 1 100 1 2 0.994 3 1 0.992 3 1 0.007 1 100 1 2 1 4 1 1 4 1 1500 2 2 0 4 1 0 4 1 1500 2 2 0.016 2 1 0.031 2 1 0.009 1 1500 2 2 0.038 2 1 0.073 2 1 0.009 1 1500 2 2 0.057 2 1 0.116 3 1 0.009 1 1500 2 2 0.083 2 1 0.162 3 1 0.008 1 1500 2 2 0.115 3 1 0.209 3 1 0.009 1 1500 2 2 0.134 3 1 0.252 3 1 0.008 1 1500 2 2 0.19 3 1 0.325 3 1 0.008 1 1500 2 2 0.226 3 1 0.368 3 1 0.008 1 1500 2 2 0.249 3 1 0.399 3 1 0.009 1 1500 2 2 0.276 3 1 0.43 3 1 0.009 1 1500 2 2 0.311 3 1 0.467 3 1 0.009 1 1500 2 2 0.366 3 1 0.52 3 1 0.009 1 1500 2 2 0.397 3 1 0.545 3 1 0.008 1 1500 2 2 0.425 3 1 0.569 3 1 0.008 1 1500 2 2 0.474 3 1 0.609 3 1 0.008 1 1500 2 2 0.5 3 1 0.63 3 1 0.007 1 1500 2 2 0.555 3 1 0.673 3 1 0.007 1 1500 2 2 0.583 3 1 0.691 3 1 0.007 1 1500 2 2 0.599 3 1 0.704 3 1 0.007 1 1500 2 2 0.615 3 1 0.717 3 1 0.006 1 1500 2 2 0.63 3 1 0.726 3 1 0.006 1 1500 2 2 0.652 3 1 0.741 3 1 0.006 1 1500 2 2 0.667 3 1 0.751 3 1 0.006 1 1500 2 2 0.681 3 1 0.762 3 1 0.006 1 1500 2 2 0.708 3 1 0.78 3 1 0.006 1 1500 2 2 0.733 3 1 0.797 3 1 0.006 1 1500 2 2 0.756 3 1 0.809 3 1 0.005 1 1500 2 2 0.77 3 1 0.817 3 1 0.006 1 1500 2 2 0.804 3 1 0.842 3 1 0.006 1 1500 2 2 0.818 3 1 0.853 3 1 0.005 1 1500 2 2 0.839 3 1 0.867 3 1 0.005 1 1500 2 2 0.86 3 1 0.882 3 1 0.005 1 1500 2 2 0.904 3 1 0.918 3 1 0.005 1 1500 2 2 0.909 3 1 0.922 3 1 0.005 1 1500 2 2 0.917 3 1 0.928 3 1 0.005 1 1500 2 2 0.933 3 1 0.942 3 1 0.005 1 1500 2 2 0.947 3 1 0.955 3 1 0.005 1 1500 2 2 0.981 3 1 0.984 3 1 0.005 1 1500 2 2 0.993 3 1 0.994 3 1 0.005 1 1500 2 2 1 4 1 1 4 24 2 1 4 1 Principal objective of the work EP EP 8/26/2019 1

Boiling temperature at pressure P, K Ebulliometric method (Recirculating still)

Liquid Direct value, X 1 Data file compiler Propagation of evaluated standard uncertainties 95 Liquid Gas 1 Mole fraction 2 Liquid 2 Pressure, kPa Liquid 1 0 4 2 100 1 1 371.91 5 1 0.34 1 0.005 1 2 100 1 1 371.27 5 1 0.55 1 0.024 2 2 100 1 1 369.2 5 1 0.52 1 0.047 2 2 100 1 1 367.05 5 1 0.46 1 0.075 2 2 100 1 1 365.19 5 1 0.43 1 0.101 3 2 100 1 1 363.43 5 1 0.4 1 0.141 3 2 100 1 1 361.37 5 1 0.38 1 0.198 3 2 100 1 1 359.01 5 1 0.36 1 0.284 3 2 100 1 1 356.18 5 1 0.35 1 0.315 3 2 100 1 1 355.26 5 1 0.34 1 0.348 3 2 100 1 1 354.48 5 1 0.33 1 0.385 3 2 100 1 1 353.7 5 1 0.33 1 0.422 3 2 100 1 1 353.02 5 1 0.33 1 0.444 3 2 100 1 1 352.67 5 1 0.33 1 0.469 3 2 100 1 1 352.29 5 1 0.32 1 0.509 3 2 100 1 1 351.72 5 1 0.32 1 0.547 3 2 100 1 1 351.3 5 1 0.32 1 0.619 3 2 100 1 1 350.45 5 1 0.32 1 0.661 3 2 100 1 1 350.13 5 1 0.31 1 0.686 3 2 100 1 1 349.95 5 1 0.31 1 0.728 3 2 100 1 1 349.68 5 1 0.31 1 0.762 3 2 100 1 1 349.51 5 1 0.31 1 0.792 3 2 100 1 1 349.39 5 1 0.31 1 0.816 3 2 100 1 1 349.33 5 1 0.31 1 0.839 3 2 100 1 1 349.3 5 1 0.31 1 0.867 3 2 100 1 1 349.32 5 1 0.31 1 0.895 3 2 100 1 1 349.44 5 1 0.31 1 0.944 3 2 100 1 1 349.66 5 1 0.31 1 0.971 3 2 100 1 1 349.9 5 1 0.31 1 0.994 3 2 100 1 1 350.14 5 1 0.31 1 1 4 2 100 1 1 350.19 5 1 0.3 1 0 4 2 1500 2 1 504.65 5 1 0.62 1 0.016 2 2 1500 2 1 502.65 5 1 0.78 1 0.038 2 2 1500 2 1 500.15 5 1 0.77 1 0.057 2 2 1500 2 1 498.05 5 1 0.74 1 0.083 2 2 1500 2 1 495.65 5 1 0.7 1 0.115 3 2 1500 2 1 493.25 5 1 0.72 1 0.134 3 2 1500 2 1 490.75 5 1 0.66 1 0.19 3 2 1500 2 1 487.85 5 1 0.64 1 0.226 3 2 1500 2 1 485.55 5 1 0.65 1 0.249 3 2 1500 2 1 484.25 5 1 0.63 1 0.276 3 2 1500 2 1 482.75 5 1 0.63 1 0.311 3 2 1500 2 1 480.95 5 1 0.62 1 0.366 3 2 1500 2 1 478.25 5 1 0.61 1 0.397 3 2 1500 2 1 476.85 5 1 0.6 1 0.425 3 2 1500 2 1 475.65 5 1 0.6 1 0.474 3 2 1500 2 1 473.75 5 1 0.59 1 0.5 3 2 1500 2 1 472.8 5 1 0.58 1 0.555 3 2 1500 2 1 470.93 5 1 0.57 1 0.583 3 2 1500 2 1 470.12 5 1 0.57 1 0.599 3 2 1500 2 1 469.64 5 1 0.57 1 0.615 3 2 1500 2 1 469.15 5 1 0.56 1 0.63 3 2 1500 2 1 468.81 5 1 0.56 1 0.652 3 2 1500 2 1 468.22 5 1 0.56 1 0.667 3 2 1500 2 1 467.9 5 1 0.56 1 0.681 3 2 1500 2 1 467.48 5 1 0.56 1 0.708 3 2 1500 2 1 466.87 5 1 0.55 1 0.733 3 2 1500 2 1 466.34 5 1 0.55 1 0.756 3 2 1500 2 1 465.97 5 1 0.55 1 0.77 3 2 1500 2 1 465.71 5 1 0.55 1 0.804 3 2 1500 2 1 465.09 5 1 0.55 1 0.818 3 2 1500 2 1 464.86 5 1 0.54 1 0.839 3 2 1500 2 1 464.55 5 1 0.54 1 0.86 3 2 1500 2 1 464.3 5 1 0.54 1 0.904 3 2 1500 2 1 463.73 5 1 0.54 1 0.909 3 2 1500 2 1 463.66 5 1 0.54 1 0.917 3 2 1500 2 1 463.57 5 1 0.54 1 0.933 3 2 1500 2 1 463.42 5 1 0.53 1 0.947 3 2 1500 2 1 463.24 5 1 0.53 1 0.981 3 2 1500 2 1 462.87 5 1 0.53 1 0.993 3 2 1500 2 1 462.79 5 1 0.53 1 1 4 2 1500 2 1 462.75 5 1 0.53