Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Acetoguanamine in Twelve Neat Solvents from 283.15 to 323.15 K

Yao, W.[Wenzhi], Song, N.[Nan], Xie, J.[Ju], Zhao, H.[Hongkun], Li, X.[Xinbao]
J. Chem. Eng. Data 2019, 64, 10, 4546-4550
ABSTRACT
By using the shake-flask method, the acetoguanamine solubilities in water, acetonitrile, methanol, n-butanol, isopropanol, isobutanol, ethanol, n-propanol, N,N-dimethylformamide (DMF), 1,4-dioxane, ethyl acetate, ethylene glycol (EG) were acquired over the temperatures from 283.15 K to 323.15 K at ambient pressure (p = 101.2 kPa). The mole fraction of acetoguanamine in equilibrated liquor increased as the temperature increased and followed the order in different solvents: DMF greater than EG greater than ethyl acetate greater than 1.4-dioxane greater than n-butanol greater than isobutanol greater than n-propanol greater than isopropanol greater than ethanol greater than methanol greater than water greater than acetonitrile. The acquired solubility was correlated via the Apelblat equation. The largest root-mean-square deviation value and largest relative average deviation were, respectively, 28.12x10-6 and 2.38x10-2.
Compounds
# Formula Name
1 C4H7N5 6-methyl-1,3,5-triazine-2,4-diamine
2 CH4O methanol
3 C2H6O ethanol
4 C3H8O propan-2-ol
5 C4H10O 2-methyl-1-propanol
6 C3H8O propan-1-ol
7 C4H10O butan-1-ol
8 C3H7NO dimethylformamide
9 C2H3N acetonitrile
10 C4H8O2 1,4-dioxane
11 C4H8O2 ethyl acetate
12 C2H6O2 1,2-ethanediol
13 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 6
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 4
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 7
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 5
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 9
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 12
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 8
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 10
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 11
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 1
  • 13
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9