ABSTRACT

The solubilities of 1,3,5-trifluoro-2,4,6-triiodobenzen (IFB) in twelve pure organic solvents including methanol, ethanol, acetone, toluene, ethyl acetate (EtOAc), 1,4-dioxane, 1,2-dichloroethane, acetonitrile, tetrahydrofuran (THF), 1-propanol, 2-propanol, and n-hexane were determined from (289.25 to 332.15) K at atmospheric pressure using the synthetic method. It was found that the solubilities of IFB in different solvents increase with the increasing temperature. The experimental solubilities of IFB were regressed by the modified Apelblat equation, eh equation and Wilson model. The modified Apelblat equation fits the best with the experimental solubilities of IFB with the average relative deviations (ARD) less than 1.44 %.

Compounds

#	Formula	Name
1	C6F3I3	1,3,5-trifluoro-2,4,6-triiodobenzene
2	CH4O	methanol
3	C2H6O	ethanol
4	C3H6O	acetone
5	C7H8	toluene
6	C4H8O2	ethyl acetate
7	C2H3N	acetonitrile
8	C4H8O	tetrahydrofuran
9	C3H8O	propan-1-ol
10	C3H8O	propan-2-ol
11	C6H14	hexane
12	C4H8O2	1,4-dioxane
13	C2H4Cl2	1,2-dichloroethane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Triple point temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC	1
POMD	1	Molar enthalpy of transition or fusion, kJ/mol ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC	1
POMD	1 2	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	12
POMD	1 3	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	12
POMD	1 4	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	12
POMD	1 5	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	12
POMD	1 6	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	12
POMD	1 12	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	12
POMD	1 13	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	12
POMD	1 7	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	9
POMD	1 8	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	9
POMD	1 9	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	9
POMD	1 10	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	9
POMD	1 11	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	9

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Determination and Correlation of Solubilities of 1,3,5-Trifluoro-2,4,6-triiodobenzene in Different Solvents from 289.25 to 332.15 K

Zhang, Y.[Yu], Liu, J.-Q.[Jin-Qiang], Wang, W.[Weizhou]

ABSTRACT