Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

ABSTRACT

PvT properties, vapor pressures, and saturated densities for a new low-GWP refrigerant; R1224yd(Z) (cis1-chloro-2,3,3,3-tetrafluoropropene; CF3CF=CHCl), were measured. Forty-six PvT property data were obtained along four lower density isochores in the superheat region; 22, 48, 55, and 103 kg*m-3, and three higher density isochores in the compressed liquid region; 970, 1107, and 1197 kg*m-3 at pressures up to 6.4 MPa. Fifteen vapor pressure data were obtained in the temperature range from 310 to 410 K and at pressures up to 2393 kPa, and a vapor pressure correlation was formulated based on these vapor pressure measurements. Saturated vapor and liquid densities were directly measured by the visual observation of vapor-liquid meniscus disappearance in the critical region, and also graphically determined by the intersections of the vapor pressure curve and the isochores of the PvT properties. In addition, the critical temperature Tc = 428.69 0.02 K, the critical density c = 535 5 kg*m-3, and the critical pressure Pc = 3331 3 kPa for R1224yd(Z) were determined.