Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Heat Capacity, Density, Vapor Pressure, and Enthalpy of Vaporization of Isoamyl dl-Lactate

Xu, J.[Jumei], Li, S.[Shating], Zeng, Z.[Zuoxiang], Xue, W.[Weilan]
J. Chem. Eng. Data 2019, 64, 9, 3793-3798
ABSTRACT
The heat capacity and the density of isoamyl lactate were measured at a temperature range of 288.15 to 453.65 K using adiabatic calorimeter and capillary pycnometer, respectively. The Antoine equation was used to correlate the vapor pressure data which was determined with an ebulliometric technique at a temperature range of 374.59 to 478.56 K, and the deviation between the calculated value and the experimental data was less than 0.87%. On basis of the Clausius-Clapeyron equation, the vaporization enthalpy of isoamyl lactate at normal pressure boiling point (Tb, 474.89 K) was calculated to be 43.27 kJ/mol. According to the Othmer's method, the standard vaporization enthalpy vapH (298.15 K) was estimated using octanol and heptanol as reference substances, and the results are 57.21 kJ/mol and 57.35 kJ/mol, respectively.
Compounds
# Formula Name
1 C8H16O3 isopentyl 2-hydroxypropanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Vacuum adiabatic calorimetry
  • 34
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 31
  • POMD
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 22