Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Viscosity Measurement and Correlation of Unloaded and CO2-Loaded Aqueous Solutions of N-Methyldiethanolamine-Piperazine

Kummamuru, N. B.[Nithin B.], Idris, Z.[Zulkifli], Eimer, D. A.[Dag A.]
J. Chem. Eng. Data 2019, 64, 11, 4692-4700
ABSTRACT
New and complementary viscosity data for aqueous N-methyldiethanolamine-piperazine (MDEA-PZ) solutions with and without CO2 are presented in this paper for different temperatures and mass fractions. The first part of this work represents viscosity of pure and aqueous MDEA to validate the measurement system. The second part represents viscosity of unloaded aqueous MDEA-PZ solutions with total mass fractions of MDEA ranging from 0.20 to 0.40 and PZ mass fractions at 0.05 and 0.1. Two different techniques for representing viscosity of the unloaded systems are discussed. The third part of this paper reports viscosities of CO2-loaded aqueous MDEA-PZ at different CO2 loadings. These data were correlated using a modified Setschenow equation.
Compounds
# Formula Name
1 H2O water
2 C4H10N2 piperazine
3 C5H13NO2 N-methyldiethanolamine
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 19
  • POMD
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 144
  • POMD
  • 2
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 90