2
0
2019
ogu
aru
0
journal
Original
Ogundele, O. P.[Oriyomi Pelumi]
Arumugam, V.[Vasanthakumar]
Moodley, K. G.[Kandasamy G.]
Redhi, G. G.[Gan G.]
Gao, Y.[Yanan]
J. Chem. Eng. Data
2019
2020-09-29
Probe of Interactions of Acetic and Propionic Acids with 2',3'-N-Epoxypropyl-N-methyl-2-oxopyrrolidinium Salicylate Ionic Liquid
Volatile organic compounds (VOCs), which find uses in industrial process need to be replaced, to decrease environmental pollution. Ionic liquids (ILs) are promising alternatives in industrial processes involving carboxylic acids. It is thus useful to study the interactions of ILs with organic acids on a laboratory scale. The combination of ILs with carboxylic acids will reduce the basicity and viscosity of ILs and thus make them suitable for many more applications in industrial processes. The thermo-physical properties namely density and speed of sound were measured for IL, [EPMpyr]+[SAL]-, and its two binary-mixtures with acetic and propionic acid. These thermophysical properties were measured at different temperatures, at 5 K intervals, ranging from T = (293.15 - 313.15) K. From these experimental values, thermodynamic parameters such as isentropic compressibility ( ), deviation in isentropic compressibility ( ) and excess molar volume ( ) were computed. It was found that and decreased with increasing temperatures and gave negative values for entire composition of both binary systems. These derived thermodynamic parameters ( & ) have been correlated using the Redlich-Kister model to obtain binary coefficients and standard errors. Keywords: Ionic liquids, Densities, Speeds of sound, Thermo-physical properties, Carboxylic acids, Inter-molecular interactions
Ionic liquids
Densities
Speeds of sound
Thermo-physical properties
Carboxylic acids
Inter-molecular interactions
10.1021/acs.jced.8b01204
12
64
5028-5037
1
InChI=1S/C8H14NO2.C7H6O3/c1-9(5-7-6-11-7)4-2-3-8(9)10;8-6-4-2-1-3-5(6)7(9)10/h7H,2-6H2,1H3;1-4,8H,(H,9,10)/q+1;/p-1
YMRUMKAZFATNJX-UHFFFAOYSA-M
1-methyl-1-(oxiran-2-ylmethyl)-2-oxopyrrolidinium salicylate
N-(2',3'-epoxypropyl)-N-methyl-2-oxopyrrolidinium salicylate
C15H19NO5
1
Synthesized by the authors
1
98
2
NMR (proton)
2
InChI=1S/C2H4O2/c1-2(3)4/h1H3,(H,3,4)
QTBSBXVTEAMEQO-UHFFFAOYSA-N
acetic acid
ethanoic acid
methanecarboxylic acid
C2H4O2
1
Commercial source
1
99
2
Stated by supplier
2
Fractional distillation
3
InChI=1S/C3H6O2/c1-2-3(4)5/h2H2,1H3,(H,4,5)
XBDQKXXYIPTUBI-UHFFFAOYSA-N
propanoic acid
ethanecarboxylic acid
propionic acid
C3H6O2
1
Commercial source
1
99
2
Stated by supplier
2
Fractional distillation
1
1
1
Principal objective of the work
EP
EP
9/26/2019
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
1209.8
5
1
3.2
1
298.15
5
1
1205.5
5
1
3.2
1
303.15
5
1
1201.3
5
1
3.2
1
308.15
5
1
1197.2
5
1
3.2
1
313.15
5
1
1193
5
1
3.2
2
1
1
Principal objective of the work
EP
EP
9/26/2019
1
Speed of sound, m/s
Single path-length method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
1634.23
6
1
6.34
1
298.15
5
1
1614.45
6
1
6.34
1
303.15
5
1
1595.74
6
1
6.34
1
308.15
5
1
1577.58
6
1
6.33
1
313.15
5
1
1559.52
6
1
6.33
3
2
1
Principal objective of the work
EP
EP
9/26/2019
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
1052.5
5
1
3
1
298.15
5
1
1046.9
5
1
3
1
303.15
5
1
1041.4
5
1
3
1
308.15
5
1
1035.8
5
1
3
1
313.15
5
1
1030
5
1
3
4
2
1
Principal objective of the work
EP
EP
9/26/2019
1
Speed of sound, m/s
Single path-length method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
1159.31
6
1
6.09
1
298.15
5
1
1142.78
6
1
6.09
1
303.15
5
1
1126.27
6
1
6.09
1
308.15
5
1
1109.56
6
1
6.09
1
313.15
5
1
1094.85
6
1
6.09
5
3
1
Principal objective of the work
EP
EP
9/26/2019
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
993.8
4
1
3
1
298.15
5
1
988.4
4
1
3
1
303.15
5
1
983
4
1
3
1
308.15
5
1
977.6
4
1
3
1
313.15
5
1
972.2
4
1
3
6
3
1
Principal objective of the work
EP
EP
9/26/2019
1
Speed of sound, m/s
Single path-length method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
1
293.15
5
1
1166.35
6
1
6.09
1
298.15
5
1
1148.13
6
1
6.09
1
303.15
5
1
1129.7
6
1
6.09
1
308.15
5
1
1111.29
6
1
6.09
1
313.15
5
1
1092.8
5
1
6.1
7
1
1
2
1
Principal objective of the work
EP
EP
9/26/2019
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0
5
1
1052.5
5
1
3
1
293.15
5
2
0.0301
3
1
1080.9
5
1
3
1
293.15
5
2
0.0701
3
1
1103.7
5
1
3
1
293.15
5
2
0.1001
4
1
1117.2
5
1
3
1
293.15
5
2
0.2001
4
1
1147.6
5
1
3
1
293.15
5
2
0.3003
4
1
1166.3
5
1
3
1
293.15
5
2
0.4013
4
1
1178.7
5
1
3.1
1
293.15
5
2
0.5017
4
1
1187.3
5
1
3.1
1
293.15
5
2
0.6002
4
1
1193.9
5
1
3.1
1
293.15
5
2
0.7019
4
1
1199.1
5
1
3.1
1
293.15
5
2
0.8024
4
1
1203.6
5
1
3.2
1
293.15
5
2
0.901
4
1
1207
5
1
3.2
1
293.15
5
2
1
5
1
1209.8
5
1
3.2
1
298.15
5
2
0
5
1
1046.9
5
1
3
1
298.15
5
2
0.0301
3
1
1075.6
5
1
3
1
298.15
5
2
0.0701
3
1
1098.6
5
1
3
1
298.15
5
2
0.1001
4
1
1112.3
5
1
3
1
298.15
5
2
0.2001
4
1
1143
5
1
3
1
298.15
5
2
0.3003
4
1
1161.7
5
1
3
1
298.15
5
2
0.4013
4
1
1174.2
5
1
3.1
1
298.15
5
2
0.5017
4
1
1183
5
1
3.1
1
298.15
5
2
0.6002
4
1
1189.6
5
1
3.1
1
298.15
5
2
0.7019
4
1
1194.9
5
1
3.1
1
298.15
5
2
0.8024
4
1
1199.3
5
1
3.1
1
298.15
5
2
0.901
4
1
1202.7
5
1
3.2
1
298.15
5
2
1
5
1
1205.5
5
1
3.2
1
303.15
5
2
0
5
1
1041.4
5
1
3
1
303.15
5
2
0.0301
3
1
1070.3
5
1
3
1
303.15
5
2
0.0701
3
1
1093.5
5
1
3
1
303.15
5
2
0.1001
4
1
1107.3
5
1
3
1
303.15
5
2
0.2001
4
1
1138.3
5
1
3
1
303.15
5
2
0.3003
4
1
1157.2
5
1
3
1
303.15
5
2
0.4013
4
1
1169.7
5
1
3.1
1
303.15
5
2
0.5017
4
1
1178.7
5
1
3.1
1
303.15
5
2
0.6002
4
1
1185.4
5
1
3.1
1
303.15
5
2
0.7019
4
1
1190.7
5
1
3.1
1
303.15
5
2
0.8024
4
1
1195.1
5
1
3.1
1
303.15
5
2
0.901
4
1
1198.6
5
1
3.2
1
303.15
5
2
1
5
1
1201.3
5
1
3.2
1
308.15
5
2
0
5
1
1035.8
5
1
3
1
308.15
5
2
0.0301
3
1
1065
5
1
3
1
308.15
5
2
0.0701
3
1
1088.4
5
1
3
1
308.15
5
2
0.1001
4
1
1102.4
5
1
3
1
308.15
5
2
0.2001
4
1
1133.6
5
1
3
1
308.15
5
2
0.3003
4
1
1152.7
5
1
3
1
308.15
5
2
0.4013
4
1
1165.5
5
1
3.1
1
308.15
5
2
0.5017
4
1
1174.5
5
1
3.1
1
308.15
5
2
0.6002
4
1
1181.3
5
1
3.1
1
308.15
5
2
0.7019
4
1
1186.7
5
1
3.1
1
308.15
5
2
0.8024
4
1
1191
5
1
3.1
1
308.15
5
2
0.901
4
1
1194.5
5
1
3.2
1
308.15
5
2
1
5
1
1197.2
5
1
3.2
1
313.15
5
2
0
5
1
1030
5
1
3
1
313.15
5
2
0.0301
3
1
1059.7
5
1
3
1
313.15
5
2
0.0701
3
1
1083.3
5
1
3
1
313.15
5
2
0.1001
4
1
1097.4
5
1
3
1
313.15
5
2
0.2001
4
1
1128.8
5
1
3
1
313.15
5
2
0.3003
4
1
1148.9
5
1
3
1
313.15
5
2
0.4013
4
1
1161
5
1
3.1
1
313.15
5
2
0.5017
4
1
1170.1
5
1
3.1
1
313.15
5
2
0.6002
4
1
1177
5
1
3.1
1
313.15
5
2
0.7019
4
1
1182.5
5
1
3.1
1
313.15
5
2
0.8024
4
1
1186.7
5
1
3.1
1
313.15
5
2
0.901
4
1
1190.2
5
1
3.2
1
313.15
5
2
1
5
1
1193
5
1
3.2
8
1
1
2
1
Principal objective of the work
EP
EP
9/26/2019
1
Speed of sound, m/s
Single path-length method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0
5
1
1159.31
6
1
6.09
1
293.15
5
2
0.0301
3
1
1249.97
6
1
6.09
1
293.15
5
2
0.0701
3
1
1310.72
6
1
6.1
1
293.15
5
2
0.1001
4
1
1349.65
6
1
6.1
1
293.15
5
2
0.2001
4
1
1441.02
6
1
6.12
1
293.15
5
2
0.3003
4
1
1496.69
6
1
6.14
1
293.15
5
2
0.4013
4
1
1535.05
6
1
6.17
1
293.15
5
2
0.5017
4
1
1561.36
6
1
6.2
1
293.15
5
2
0.6002
4
1
1582.19
6
1
6.22
1
293.15
5
2
0.7019
4
1
1599.97
6
1
6.25
1
293.15
5
2
0.8024
4
1
1617.35
6
1
6.27
1
293.15
5
2
0.901
4
1
1626.79
6
1
6.3
1
293.15
5
2
1
5
1
1634.23
6
1
6.34
1
298.15
5
2
0
5
1
1142.78
6
1
6.09
1
298.15
5
2
0.0301
3
1
1232.74
6
1
6.1
1
298.15
5
2
0.0701
3
1
1294.03
6
1
6.1
1
298.15
5
2
0.1001
4
1
1333.15
6
1
6.11
1
298.15
5
2
0.2001
4
1
1424.62
6
1
6.13
1
298.15
5
2
0.3003
4
1
1480.21
6
1
6.15
1
298.15
5
2
0.4013
4
1
1515.76
6
1
6.17
1
298.15
5
2
0.5017
4
1
1541.79
6
1
6.2
1
298.15
5
2
0.6002
4
1
1562.55
6
1
6.22
1
298.15
5
2
0.7019
4
1
1581.98
6
1
6.25
1
298.15
5
2
0.8024
4
1
1599.97
6
1
6.27
1
298.15
5
2
0.901
4
1
1609.25
6
1
6.3
1
298.15
5
2
1
5
1
1614.45
6
1
6.34
1
303.15
5
2
0
5
1
1126.27
6
1
6.09
1
303.15
5
2
0.0301
3
1
1215.52
6
1
6.1
1
303.15
5
2
0.0701
3
1
1277.27
6
1
6.1
1
303.15
5
2
0.1001
4
1
1316.54
6
1
6.11
1
303.15
5
2
0.2001
4
1
1408.13
6
1
6.13
1
303.15
5
2
0.3003
4
1
1463.7
6
1
6.15
1
303.15
5
2
0.4013
4
1
1497.41
6
1
6.17
1
303.15
5
2
0.5017
4
1
1523.2
6
1
6.2
1
303.15
5
2
0.6002
4
1
1542.92
6
1
6.22
1
303.15
5
2
0.7019
4
1
1565.21
6
1
6.25
1
303.15
5
2
0.8024
4
1
1583
6
1
6.27
1
303.15
5
2
0.901
4
1
1592.25
6
1
6.3
1
303.15
5
2
1
5
1
1595.74
6
1
6.34
1
308.15
5
2
0
5
1
1109.56
6
1
6.09
1
308.15
5
2
0.0301
3
1
1198.57
6
1
6.1
1
308.15
5
2
0.0701
3
1
1260.74
6
1
6.1
1
308.15
5
2
0.1001
4
1
1300.11
6
1
6.11
1
308.15
5
2
0.2001
4
1
1391.81
6
1
6.13
1
308.15
5
2
0.3003
4
1
1447.47
6
1
6.15
1
308.15
5
2
0.4013
4
1
1480.22
6
1
6.17
1
308.15
5
2
0.5017
4
1
1504.89
6
1
6.2
1
308.15
5
2
0.6002
4
1
1528.53
6
1
6.22
1
308.15
5
2
0.7019
4
1
1548.76
6
1
6.25
1
308.15
5
2
0.8024
4
1
1566.53
6
1
6.27
1
308.15
5
2
0.901
4
1
1575.68
6
1
6.3
1
308.15
5
2
1
5
1
1577.58
6
1
6.33
1
313.15
5
2
0
5
1
1094.85
6
1
6.09
1
313.15
5
2
0.0301
3
1
1181.84
6
1
6.12
1
313.15
5
2
0.0701
3
1
1244.42
6
1
6.11
1
313.15
5
2
0.1001
4
1
1283.9
6
1
6.12
1
313.15
5
2
0.2001
4
1
1375.69
6
1
6.15
1
313.15
5
2
0.3003
4
1
1431.01
6
1
6.16
1
313.15
5
2
0.4013
4
1
1463.07
6
1
6.17
1
313.15
5
2
0.5017
4
1
1488.82
6
1
6.19
1
313.15
5
2
0.6002
4
1
1515.38
6
1
6.22
1
313.15
5
2
0.7019
4
1
1532.63
6
1
6.25
1
313.15
5
2
0.8024
4
1
1550.38
6
1
6.28
1
313.15
5
2
0.901
4
1
1559.5
6
1
6.31
1
313.15
5
2
1
5
1
1559.52
6
1
6.33
9
1
1
3
1
Principal objective of the work
EP
EP
9/26/2019
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0
5
1
993.8
4
1
3
1
293.15
5
2
0.0303
3
1
1018.7
5
1
3
1
293.15
5
2
0.0701
3
1
1046.2
5
1
3
1
293.15
5
2
0.1006
4
1
1063.4
5
1
3
1
293.15
5
2
0.2
4
1
1105.7
5
1
3
1
293.15
5
2
0.3007
4
1
1133.9
5
1
3
1
293.15
5
2
0.4009
4
1
1153.6
5
1
3.1
1
293.15
5
2
0.501
4
1
1168.6
5
1
3.1
1
293.15
5
2
0.6002
4
1
1180.6
5
1
3.1
1
293.15
5
2
0.7002
4
1
1190.5
5
1
3.1
1
293.15
5
2
0.8005
4
1
1198.3
5
1
3.1
1
293.15
5
2
0.901
4
1
1204.6
5
1
3.2
1
293.15
5
2
1
5
1
1209.8
5
1
3.2
1
298.15
5
2
0
5
1
988.4
4
1
3
1
298.15
5
2
0.0303
3
1
1013.6
5
1
3
1
298.15
5
2
0.0701
3
1
1041.2
5
1
3
1
298.15
5
2
0.1006
4
1
1058.6
5
1
3
1
298.15
5
2
0.2
4
1
1101.9
5
1
3
1
298.15
5
2
0.3007
4
1
1129.4
5
1
3
1
298.15
5
2
0.4009
4
1
1149.2
5
1
3.1
1
298.15
5
2
0.501
4
1
1164.2
5
1
3.1
1
298.15
5
2
0.6002
4
1
1176.3
5
1
3.1
1
298.15
5
2
0.7002
4
1
1186.2
5
1
3.1
1
298.15
5
2
0.8005
4
1
1194.1
5
1
3.1
1
298.15
5
2
0.901
4
1
1200.4
5
1
3.2
1
298.15
5
2
1
5
1
1205.5
5
1
3.2
1
303.15
5
2
0
5
1
983
4
1
3
1
303.15
5
2
0.0303
3
1
1008.2
5
1
3
1
303.15
5
2
0.0701
3
1
1036.2
5
1
3
1
303.15
5
2
0.1006
4
1
1053.7
5
1
3
1
303.15
5
2
0.2
4
1
1096.5
5
1
3
1
303.15
5
2
0.3007
4
1
1124.9
5
1
3
1
303.15
5
2
0.4009
4
1
1144.8
5
1
3.1
1
303.15
5
2
0.501
4
1
1159.8
5
1
3.1
1
303.15
5
2
0.6002
4
1
1172
5
1
3.1
1
303.15
5
2
0.7002
4
1
1181.9
5
1
3.1
1
303.15
5
2
0.8005
4
1
1189.8
5
1
3.1
1
303.15
5
2
0.901
4
1
1196.1
5
1
3.2
1
303.15
5
2
1
5
1
1201.3
5
1
3.2
1
308.15
5
2
0
5
1
977.6
4
1
3
1
308.15
5
2
0.0303
3
1
1003.2
5
1
3
1
308.15
5
2
0.0701
3
1
1031.3
5
1
3
1
308.15
5
2
0.1006
4
1
1048.9
5
1
3
1
308.15
5
2
0.2
4
1
1091.8
5
1
3
1
308.15
5
2
0.3007
4
1
1120.4
5
1
3
1
308.15
5
2
0.4009
4
1
1140.3
5
1
3.1
1
308.15
5
2
0.501
4
1
1155.4
5
1
3.1
1
308.15
5
2
0.6002
4
1
1167.6
5
1
3.1
1
308.15
5
2
0.7002
4
1
1177.6
5
1
3.1
1
308.15
5
2
0.8005
4
1
1185.5
5
1
3.1
1
308.15
5
2
0.901
4
1
1191.8
5
1
3.2
1
308.15
5
2
1
5
1
1197.2
5
1
3.2
1
313.15
5
2
0
5
1
972.2
4
1
3
1
313.15
5
2
0.0303
3
1
998
4
1
3
1
313.15
5
2
0.0701
3
1
1026.3
5
1
3
1
313.15
5
2
0.1006
4
1
1044
5
1
3
1
313.15
5
2
0.2
4
1
1087.2
5
1
3
1
313.15
5
2
0.3007
4
1
1115.9
5
1
3
1
313.15
5
2
0.4009
4
1
1135.9
5
1
3
1
313.15
5
2
0.501
4
1
1151
5
1
3.1
1
313.15
5
2
0.6002
4
1
1163.3
5
1
3.1
1
313.15
5
2
0.7002
4
1
1173.3
5
1
3.1
1
313.15
5
2
0.8005
4
1
1181.2
5
1
3.1
1
313.15
5
2
0.901
4
1
1187.5
5
1
3.2
1
313.15
5
2
1
5
1
1193
5
1
3.2
10
1
1
3
1
Principal objective of the work
EP
EP
9/26/2019
1
Speed of sound, m/s
Single path-length method
Liquid
Direct value, X
1
Data file compiler
Propagation of evaluated standard uncertainties
95
Liquid
1
Pressure, kPa
Liquid
101
3
1
Temperature, K
Liquid
2
Mole fraction
1
Liquid
1
293.15
5
2
0
5
1
1166.35
6
1
6.09
1
293.15
5
2
0.0303
3
1
1211.89
6
1
6.1
1
293.15
5
2
0.0701
3
1
1266.69
6
1
6.1
1
293.15
5
2
0.1006
4
1
1303.51
6
1
6.11
1
293.15
5
2
0.2
4
1
1400.32
6
1
6.12
1
293.15
5
2
0.3007
4
1
1465.81
6
1
6.14
1
293.15
5
2
0.4009
4
1
1505.74
6
1
6.17
1
293.15
5
2
0.501
4
1
1538.85
6
1
6.19
1
293.15
5
2
0.6002
4
1
1565.39
6
1
6.22
1
293.15
5
2
0.7002
4
1
1584.49
6
1
6.25
1
293.15
5
2
0.8005
4
1
1599.72
6
1
6.27
1
293.15
5
2
0.901
4
1
1615.39
6
1
6.31
1
293.15
5
2
1
5
1
1634.23
6
1
6.34
1
298.15
5
2
0
5
1
1148.13
6
1
6.09
1
298.15
5
2
0.0303
3
1
1193.4
6
1
6.1
1
298.15
5
2
0.0701
3
1
1248.69
6
1
6.11
1
298.15
5
2
0.1006
4
1
1286.04
6
1
6.11
1
298.15
5
2
0.2
4
1
1383.27
6
1
6.13
1
298.15
5
2
0.3007
4
1
1448.95
6
1
6.15
1
298.15
5
2
0.4009
4
1
1488.91
6
1
6.17
1
298.15
5
2
0.501
4
1
1521.86
6
1
6.2
1
298.15
5
2
0.6002
4
1
1547.77
6
1
6.22
1
298.15
5
2
0.7002
4
1
1566.76
6
1
6.25
1
298.15
5
2
0.8005
4
1
1581.66
6
1
6.27
1
298.15
5
2
0.901
4
1
1596.41
6
1
6.3
1
298.15
5
2
1
5
1
1614.45
6
1
6.34
1
303.15
5
2
0
5
1
1129.7
6
1
6.09
1
303.15
5
2
0.0303
3
1
1175
6
1
6.1
1
303.15
5
2
0.0701
3
1
1230.82
6
1
6.11
1
303.15
5
2
0.1006
4
1
1268.48
6
1
6.11
1
303.15
5
2
0.2
4
1
1366.14
6
1
6.13
1
303.15
5
2
0.3007
4
1
1432.01
6
1
6.15
1
303.15
5
2
0.4009
4
1
1472.04
6
1
6.17
1
303.15
5
2
0.501
4
1
1504.95
6
1
6.2
1
303.15
5
2
0.6002
4
1
1530.94
6
1
6.22
1
303.15
5
2
0.7002
4
1
1549.51
6
1
6.25
1
303.15
5
2
0.8005
4
1
1564.16
6
1
6.27
1
303.15
5
2
0.901
4
1
1578.57
6
1
6.3
1
303.15
5
2
1
5
1
1595.74
6
1
6.34
1
308.15
5
2
0
5
1
1111.29
6
1
6.09
1
308.15
5
2
0.0303
3
1
1156.83
6
1
6.1
1
308.15
5
2
0.0701
3
1
1213.19
6
1
6.11
1
308.15
5
2
0.1006
4
1
1251.11
6
1
6.11
1
308.15
5
2
0.2
4
1
1349.2
6
1
6.13
1
308.15
5
2
0.3007
4
1
1415.27
6
1
6.15
1
308.15
5
2
0.4009
4
1
1455.41
6
1
6.17
1
308.15
5
2
0.501
4
1
1488.36
6
1
6.2
1
308.15
5
2
0.6002
4
1
1514.29
6
1
6.22
1
308.15
5
2
0.7002
4
1
1532.71
6
1
6.25
1
308.15
5
2
0.8005
4
1
1547.26
6
1
6.27
1
308.15
5
2
0.901
4
1
1561.46
6
1
6.3
1
308.15
5
2
1
5
1
1577.58
6
1
6.33
1
313.15
5
2
0
5
1
1092.8
5
1
6.1
1
313.15
5
2
0.0303
3
1
1138.91
6
1
6.1
1
313.15
5
2
0.0701
3
1
1195.81
6
1
6.11
1
313.15
5
2
0.1006
4
1
1233.65
6
1
6.12
1
313.15
5
2
0.2
4
1
1332.5
6
1
6.15
1
313.15
5
2
0.3007
4
1
1398.73
6
1
6.16
1
313.15
5
2
0.4009
4
1
1438.98
6
1
6.17
1
313.15
5
2
0.501
4
1
1472
6
1
6.2
1
313.15
5
2
0.6002
4
1
1497.93
6
1
6.22
1
313.15
5
2
0.7002
4
1
1516.33
6
1
6.25
1
313.15
5
2
0.8005
4
1
1530.79
6
1
6.27
1
313.15
5
2
0.901
4
1
1544.9
6
1
6.3
1
313.15
5
2
1
5
1
1559.52
6
1
6.33