Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

High Pressure Phase Equilibrium Data for the Ternary System Containing Carbon Dioxide, Dichloromethane, and epsilon-Caprolactone

Mayer, Diego Alex, Rebelatto, Evertan Antonio, Ndiaye, Papa Matar, Lanza, Marcelo, Oliveira, Debora de, Souza, Selene M. A. Guelli U. de, Oliveira, Jose Vladimir

J. Chem. Eng. Data 2019, 64, 5, 2036-2044

ABSTRACT

This work reports experimental phase equilibrium data the for ternary system involving caprolactone, carbon dioxide and dichloromethane. Such data provide fundamental information to conduct polymerization reactions in supercritical carbon dioxide medium. The experiments were performed using a variable-volume view cell over the temperature range from 323.15 to 353.15 K and different mass ratios of dichloromethane to -caprolactone (0.5:1, 1:1 and 2:1). Phase transitions of vapor-liquid at the bubble point (VLE-PB), liquid-liquid (LLE) and vaporliquid-liquid (VLLE) types were observed. The experimental results were modelled using the Peng-Robinson EoS with the van der Waals mixing rule, resulting in a good representation of experimental phase equilibrium data.

Compounds

#	Formula	Name
1	C6H10O2	6-hexanolactone
2	CH2Cl2	dichloromethane
3	CO2	carbon dioxide

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	3 1 2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 1; Liquid	Liquid Gas	Closed cell (Static) method	64
POMD	3 1 2	Vapor or sublimation pressure, kPa ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mass fraction - 3; Liquid mixture 1 Mass fraction - 1; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Closed cell (Static) method	31
POMD	3 1 2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 1; Liquid	Liquid Gas	Closed cell (Static) method	40