Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isothermal Bubble Pressure Data for the Binary System of C2F6 and n-Octane

Williams-Wynn, Mark D., Naidoo, Paramespri, Ramjugernath, Deresh
J. Chem. Eng. Data 2018, 63, 12, 4795-4800
ABSTRACT
Bubble pressure data for the system of hexafluoroethane and n-octane were measured at four temperatures in the range of (292.9 to 323.4) K, and at pressures of up to 5.6 MPa. These isothermal P-x data were measured using a variable-volume static-synthetic apparatus. The Peng-Robinson Equation of State, modified with the Mathias-Copeman alpha function, coupled to the Wong-Sandler mixing rule, was used to model the experimental data. The Non-Random TwoLiquid activity coefficient model was used to model the excess Gibbs energy term within the WongSandler mixing rule. The temperature dependency of the thermodynamic model parameters was investigated at the temperatures for which data were measured. The binary system was categorised according to the van Konynenburg and Scott classification system.
Compounds
# Formula Name
1 C2F6 hexafluoroethane
2 C8H18 octane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 2
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 5
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 31