Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurements of PvT Properties, Saturated Densities, and Critical Parameters for 3,3,3-Trifluoropropene (HFO1243zf)

Higashi, Yukihiro, Sakoda, Naoya
J. Chem. Eng. Data 2018, 63, 10, 3818-3822
ABSTRACT
Measurements of PvT properties, saturated densities and critical parameters were carried out for a lowGWP refrigerant: 3,3,3-trifluoropropene (HFO1243zf, CF3CH=CH2). Seventy-five PvT property data along 7 isochores around the critical point were obtained in the temperature range from 328 K to 430 K, in the density range between 50 kg*m-3 and 899 kg*m-3, and at pressures up to 6.9 MPa by the isochoric method. Fourteen saturated densities were obtained by the observation of meniscus disappearance in the critical region. On the basis of these measurements, the critical parameters of Tc = 376.93 K and c = 414 kg*m-3 were determined. The experimental data obtained are compared with an available equation of state
Compounds
# Formula Name
1 C3H3F3 1,1,1-trifluoro-2-propene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 42
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • ISOCHOR
  • 21
  • POMD
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • ISOCHOR
  • 8
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • ISOCHOR
  • 7
  • POMD
  • 1
  • Mass density, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • ISOCHOR
  • 12