ABSTRACT

The solubility data of -2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane in six binary solvents (n-hexane, n-heptane, n-octane, isooctane, cyclohexane, and methylbenzene mixed with various mole fractions of ethyl acetate, respectively) was experimentally studied by the gravimetric method at temperatures ranging from 283.15 to 323.15 K, under an atmosphere pressure of 0.1 MPa. The results of these measurements were correlated with the modified Apelblat equation, CNIBS/R-K equation and the Jouyban-Acree model. All three models provide a satisfactory correlation.

Compounds

#	Formula	Name
1	C6H6N12O12	2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane
2	C4H8O2	ethyl acetate
3	C6H14	hexane
4	C7H16	heptane
5	C8H18	octane
6	C8H18	2,2,4-trimethylpentane
7	C6H12	cyclohexane
8	C7H8	toluene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 3 2	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	81
POMD	1 4 2	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	81
POMD	1 5 2	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	81
POMD	1 6 2	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	81
POMD	1 7 2	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	81
POMD	1 8 2	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	81
POMD	1 2	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	gravimetric	9

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility Measurement and Correlation for epsilon-2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane in Different Alkanes/Aromatic Hydrocarbon + Ethyl Acetate Binary Solvents at Temperatures of between 283.15 and 323.15 K

Cui, Chao, Ren, Hui, Jiao, Qingjie

ABSTRACT