Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental Study of Carbon Dioxide Solubility in Aqueous N-Methyldiethanolamine Solution with 1-Butylpyridinium Tetrafluoroborate Ionic Liquid

Damanafshan, Milad, Mokhtarani, Babak, Mirzaei, Mojtaba, Mafi, Morteza, Sharifi, Ali, Jalili, Amir Hossein
J. Chem. Eng. Data 2018, 63, 6, 2135-2150
ABSTRACT
New experimental data for CO2 solubility in the aqueous solutions of N-Methyldiethanolamine (MDEA) and 1-Butylpyridinium tetrafluoroborate ([Bpy][BF4]) ionic liquid (IL) are reported. The experiments were conducted in a static high pressure equilibrium cell. Solubility of CO2 was performed in various solution's compositions of IL and MDEA at a wide temperature range of (298.15 to 343.15) K and pressures up to 4 MPa. The experimental results revealed that by increasing weight percent of IL, the absorption capacity of aqueous mixtures diminishes. It was also observed that the main capacity of CO2 loading in the absorbent solutions belonged to MDEA through chemical absorption whereas its concentration was more effective than IL in gas solubility. The experimental results are correlated using a semi empirical model with a good accuracy.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 C5H13NO2 N-methyldiethanolamine
3 C9H14BF4N 1-butylpyridinium tetrafluoroborate
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 5
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 5
  • POMD
  • 2
  • 3
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 43
  • POMD
  • 2
  • 4
  • 1
  • Molality, mol/kg - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Liquid
  • Gas
  • phase equilibration
  • 80
  • POMD
  • 2
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 13