Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Viscosity, and N2O Solubility of Aqueous Solutions of MEA, BmimBF4, and Their Mixtures from 293.15 to 333.15 K

Xu, Lingjun, Wang, Shujuan
J. Chem. Eng. Data 2018, 63, 8, 2708-2717
ABSTRACT
Densities and viscosities of aqueous solutions of Ethanolamine (MEA), 1-Butyl-3-methylimidazolium tetrafluoroborate (BmimBF4), and their mixtures were measured. The experiments covered the mole fraction ranges: 1.00-9.38 mol% of BmimBF4 in its aqueous solutions, 3.94-21.97 mol% of MEA in its aqueous solutions, and 1.32-17.01 mol% of MEA + 5.10-34.02 mol% of BmimBF4 in the mixtures. The results are compared with available data in literatures and correlated using semiempirical formula as functions of temperature and concentration of MEA and BmimBF4. At the concentration suitable for the CO2 capture, the viscosity of the hybrid absorbent did not significantly increased by the addition of BmimBF4. Moreover, the addition of BmimBF4 reduced the Henry constant, which is significant for reaction kinetics.
Compounds
# Formula Name
1 C8H15BF4N2 1-butyl-3-methylimidazolium tetrafluoroborate
2 C2H7NO 2-aminoethan-1-ol
3 N2O nitrous oxide
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 45
  • POMD
  • 1
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Oscillating disk viscometry
  • 45
  • POMD
  • 2
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 36
  • POMD
  • 2
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Oscillating disk viscometry
  • 36
  • POMD
  • 1
  • 2
  • 4
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 54
  • POMD
  • 1
  • 2
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Oscillating disk viscometry
  • 54
  • POMD
  • 3
  • 1
  • 4
  • Mole fraction - 3 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Phase equilibration
  • 20
  • POMD
  • 3
  • 2
  • 4
  • Mole fraction - 3 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Phase equilibration
  • 16
  • POMD
  • 3
  • 4
  • Mole fraction - 3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Phase equilibration
  • 5