ABSTRACT

Present work reports experimental isobaric vapor-liquid equilibrium data at 93.9 kPa pressure using a dynamic recirculation still for four binary pairs of acetates with anisole. Suitability of the experimental data for modelling was established by performing Herington area test, Van Ness test and mean absolute deviation test. Binary interaction parameters necessary for process modelling were derived through regression of the VLE data for Wilson, NRTL, and UNIQUAC activity coefficient models with a suitable objective function. VLE data in the form of T-x,y plots indicates no formation of azeotrope for all pairs.

Compounds

#	Formula	Name
1	C7H8O	anisole
2	C3H6O2	methyl ethanoate
3	C4H8O2	ethyl acetate
4	C5H10O2	propyl ethanoate
5	C5H10O2	1-methylethyl ethanoate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	1	Refractive index (Na D-line) ; Liquid		Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	2
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	13
POMD	2 1	Mole fraction - 2 ; Gas	Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Gas Liquid	Index of refraction calibration data	13
POMD	2 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	17
POMD	3 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	13
POMD	3 1	Mole fraction - 3 ; Gas	Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Gas Liquid	Index of refraction calibration data	13
POMD	3 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	19
POMD	4 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	13
POMD	4 1	Mole fraction - 4 ; Gas	Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Gas Liquid	Index of refraction calibration data	13
POMD	4 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	18
POMD	5 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	13
POMD	5 1	Mole fraction - 5 ; Gas	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Gas Liquid	Index of refraction calibration data	13
POMD	5 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	18

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isobaric Vapor-Liquid Equilibrium Data for Binary Systems of Anisole with Methyl Acetate, Ethyl Acetate, n-Propyl Acetate, and Isopropyl Acetate at 93.9 kPa

Bhoi, Bharat R., Mali, Nilesh A., Joshi, Sunil S.

ABSTRACT