Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities and Viscosities for Binary Liquid Mixtures of Biodiesel + 1-Pentanol, 2-Pentanol, or 2-Methyl-1-Butanol from (288.15 to 338.15) K at 0.1 MPa

Vargas-Ibanez, Leidy T., Iglesias-Silva, Gustavo A., Cano-Gomez, Jose J., Escamilla-Alvarado, Carlos, Berrones-Eguiluz, Miguel A.
J. Chem. Eng. Data 2018, 63, 7, 2438-2450
ABSTRACT
This work presents experimentally determined densities and viscosities of biodiesel blended with 1-pentanol, 2-pentanol, and 2-methyl-1-butanol between 288.15 and 338.15 K at 0.1 MPa. The densities are measured using a vibrating tube densimeter, and the kinematic viscosities using a glass capillary viscometer. The measured density and viscosity of the pure components agree with values reported in the literature within an average absolute percentage deviation of 0.04 % and 0.83 %, respectively. The excess molar volumes and viscosity deviations show positive and negative deviations from the ideality, respectively. The Redlich-Kister equation is used to represent the composition behavior of the excess molar volumes and viscosity deviations. The experimental kinematic viscosities have a minimum value over a composition range of 50-90 % alcohol by weight. The McAllister equation correlates the kinematic viscosity within an average absolute percentage deviation of 1.77 %, while the Nava-Rios equation correlates the kinematic viscosity within 0.88 %.
Compounds
# Formula Name
1 C5H12O pentan-1-ol
2 C5H12O pentan-2-ol
3 C5H12O 2-methyl-1-butanol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 11
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 11
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 11
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 11
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 11
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 11